di-tert-butyl peroxide in further solvent(s)
Kinetics; byproducts: t-butanol; Irradiation (UV/VIS); flash photolysis with light pulses (50 Hz, 308 nm, 10 ns duration, XeClexcimer laser) in cyclopropane-t-pentyl alcohol soln. (3:1) at 224 K, or in cyclopropane-t-pentyl alcohol-t-BuOH soln. (6:2:1), or in cyclopropane-oxirane soln. (3:1); detected by ESR spectroscopy;;
参考文献
Baban, Jehan A.; Goddard, Jeffrey P.; Roberts, Brian P.
Journal of Chemical Research, Synopses, 1986 , p. 30 - 31
Baldwin, Roy R.; Walker, Raymond W.; Walker, Robert W.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , vol. 77, p. 2157 - 2174
Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833
di-tert-butyl peroxide in various solvent(s)
T=26.85°C; radical generation; Photolysisproducts were determined by spectr. methods; Product distributionKineticsActivation energy; Further Variations:ReagentsTemperatures;
参考文献
Jackson, Leon; Walton, John C.
Tetrahedron Letters, 1999 , vol. 40, # 38 p. 7019 - 7021
