1: 2-cyanophenyl bromide With n-butyllithium in tetrahydrofuran; hexane T=-100 - -78°C; 0.55 h; Inert atmosphere; 2: zinc dibromide in tetrahydrofuran; hexane T=-100 - -78°C; 1 h; Inert atmosphere;
参考文献
Stadler, Alexander; Yousefi, Behrooz H.; Dallinger, Doris; Walla, Peter; Van Der Eycken, Erik; Kaval, Nadya; Kappe, C. Oliver
Organic Process Research and Development, 2003 , vol. 7, # 5 p. 707 - 716
in tetrahydrofuran other Radiation; microwave-accelerated preparation of arylzinc bromide by Rieke zinc insertion into aryl bromide under sealed vessel conditions for 10 min; THF 180°C; HPLC or MS;
参考文献
Walla, Peter; Kappe, C. Oliver
Chemical Communications, 2004 , # 5 p. 564 - 565
1: dimethylamine borane With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: 2-cyanophenyl bromide in tetrahydrofuran; hexane T=65°C; 12 h; Further stages.;
参考文献
Thomas; Collins; Cuzens; Spiciarich; Goralski; Singaram
Journal of Organic Chemistry, 2001 , vol. 66, # 6 p. 1999 - 2004
