2,3,5-三甲基苯甲醚合成路线 （共 26 条）
反应条件
sodium hydride in dimethyl sulfoxide 10 h; Ambient temperature;
参考文献
Fujino, Masahiko; Wakimasu, Mitsuhiro; Kitada, Chieko
Chemical & Pharmaceutical Bulletin, 1981 , vol. 29, # 10 p. 2825 - 2831
反应条件
1: 90.7 percent / conc. H2SO4, 98percent aq. HNO3 / CHCl3 / 2 h / 0 °C 2: 75.5 percent / NaOH, H2 / Raney Ni / ethanol / 114000 Torr 3: 1.) 25percent aq, H2SO4, aq. NaNO2, 2.) 20percent aq. H2SO4 / 1.) 0 deg C, 1 h, 2.) reflux, 2 h 4: 98 percent / NaH / dimethylsulfoxide / 10 h View Scheme
参考文献
Russian Journal of Organic Chemistry, , vol. 29, # 4 p. 572 - 575
Zhurnal Organicheskoi Khimii, , vol. 29, # 4 p. 682 - 686
反应条件
1: 75.5 percent / NaOH, H2 / Raney Ni / ethanol / 114000 Torr 2: 1.) 25percent aq, H2SO4, aq. NaNO2, 2.) 20percent aq. H2SO4 / 1.) 0 deg C, 1 h, 2.) reflux, 2 h 3: 98 percent / NaH / dimethylsulfoxide / 10 h View Scheme
参考文献
Russian Journal of Organic Chemistry, , vol. 29, # 4 p. 572 - 575
Zhurnal Organicheskoi Khimii, , vol. 29, # 4 p. 682 - 686
反应条件
potassium hydroxide 0.5 h; Heating;
参考文献
Bestmann; Ermann
1984 , vol. 1984, # 10 p. 1740 - 1745
反应条件
1: 1.) 25percent aq, H2SO4, aq. NaNO2, 2.) 20percent aq. H2SO4 / 1.) 0 deg C, 1 h, 2.) reflux, 2 h 2: 98 percent / NaH / dimethylsulfoxide / 10 h View Scheme
参考文献
Russian Journal of Organic Chemistry, , vol. 29, # 4 p. 572 - 575
Zhurnal Organicheskoi Khimii, , vol. 29, # 4 p. 682 - 686
反应条件
peracetic acid T=70°C; 0.5 h; other reaction time: 4 h.; Product distributionKineticsThermodynamic data;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 22, # 11 p. 2071 - 2078
Zhurnal Organicheskoi Khimii, , vol. 22, # 11 p. 2306 - 2315
反应条件
peracetic acid T=50°C; 0.25 h; Product distributionKineticsThermodynamic data;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 22, # 11 p. 2071 - 2078
Zhurnal Organicheskoi Khimii, , vol. 22, # 11 p. 2306 - 2315
反应条件
sulfuric acid T=50°C; 0.5 h; effect of catalysts; MechanismThermodynamic data;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 4 p. 923 - 930,819 - 826
反应条件
1: 1.) POCl3 / 1.) 0 deg C, 2 h, 2.) 70 deg, 24 h 2: 93 percent / LiAlH4 View Scheme
参考文献
Bestmann; Ermann
1984 , vol. 1984, # 10 p. 1740 - 1745
反应条件
trichlorophosphate T=70°C; 24 h;
参考文献
Makin, S. M.; Mikerin, I. E.; Dobretsova, E. K.; Shavrygina, O. A.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 4 p. 572 - 575
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 4 p. 682 - 686
