in neat (no solvent) carborane added to BI3 (under N2), sealed tube; mixt. warmed from -190°C to room temp., heated at 120°C for 19 h; color change from pink to yellow. Further products: unidentified carborane compds.; NMR;
参考文献
Nam, Wonwoo; Onak, Thomas
Inorganic Chemistry, 1987 , vol. 26, p. 48 - 52
aluminium trichloride; chlorine in neat (no solvent) byproducts: CH3BCl2, CH2(BCl2)2; addn. of mixt. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of Cl2 gas, warmed from -190°C to room temp. for 3 h; not isolated; detected by NMR;
chlorine in neat (no solvent) addn. of mixt. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of Cl2 gas, warmed from -190°C to room temp., kept for 7 d; not isolated; detected by NMR;
trimethylamine in dichloromethane
addn. of trimethylamine to B compd.; addn. of fluoride; allowing to stand at room temp., 47d; monitoring by 11B NMR; 25percent 5-ClC2B5H6 obtained;
参考文献
Ng, Bradford; Onak, Thomas; Fuller, Keith
Inorganic Chemistry, 1985 , vol. 24, p. 4371 - 4376
