反应条件
in ethanol; water High Pressure; mixt. of Cu-salt and (C5H4NS)2 (1:1 molar ratio) in H2O/C2H5OH in sealedvessel heated to 140°C in microwave oven within 20 min (300 W), temp. kept for 1 h, vessel slowly cooled to room temp within 8 h; orange crystals of Cu6(C5H4NS)6 and yellow crystals of Cu(I)-Cu6(II) complex salt sepd., washed with ethanol and dried in air, filtrate stored at 0°C for 2 weeks, crystals of Cu2 complex and S8 isolated; elem.anal.;
参考文献
Dalton Transactions, , vol. 39, # 9 p. 2280 - 2287
