T=570°C; 0.000555556 h; further temperatures and residence times and alkylacetylenes; also with (2)H-labelled compounds; Product distributionMechanism;
in tetrahydrofuran
molar ratio acetylene/Sn-compd. 2/1, 20°C; elem. anal.;
参考文献
Zavgorodnii, V. S.; Zubova, T. P.; Simin, V. B.; Petrov, A. A.
Journal of General Chemistry USSR (English Translation), 1981 , vol. 51, p. 1765 - 1773
Zhurnal Obshchei Khimii, 1981 , vol. 51, p. 2048 - 2057
T=570°C; 0.000555556 h; further temperatures and residence times and alkylacetylenes; also with (2)H-labelled compounds; Product distributionMechanism;
1: 5-methyl-1-hexyne With n-butyllithium in tetrahydrofuran; hexane
T=-90°C;
2: dibromo-difluoro-methane in tetrahydrofuran; hexane
T=-110 - -50°C; Title compound not separated from byproducts;
参考文献
Hammond, Gerald B.
Journal of Fluorine Chemistry, 2006 , vol. 127, # 4-5 SPEC. ISS. p. 476 - 488
