[(2-溴苯氧基)甲基]环氧乙烷合成路线 (共 7 条)
反应条件
n-butyllithium; magnesium bromide in tetrahydrofuran; diethyl ether; hexane T=-78°C; warming to room temperature;
参考文献
Dhawan, Kasturi L.; Gowland, Barbara D.; Durst, Tony
Journal of Organic Chemistry, 1980 , vol. 45, # 5 p. 922 - 924
反应条件
CuI/n-Bu3P complex; naphthalenyllithium multistep reaction; other arylepoxy bromides; other Cu-reagent; other solvent; regioselectivity; intramolecular cyclization of epoxyarylcopper compounds; Product distribution;
参考文献
Rieke, Reuben D.; Stack, Douglas E.; Dawson, Bryan T.; Wu, Tse-Chong
Journal of Organic Chemistry, 1993 , vol. 58, # 9 p. 2483 - 2491
参考文献
Beasley et al.
Journal of Pharmacy and Pharmacology, 1958 , vol. 10, p. 47,59
反应条件
N(Et)4ClO4; triethylamine in acetonitrile electrolysis;
参考文献
Bhuvaneswari; Venkatachalam; Balasubramanian
Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1499 - 1502
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene T=80°C; 8 h; Yield given. Yields of byproduct given;
参考文献
Bhuvaneswari; Venkatachalam; Balasubramanian
Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1499 - 1502
反应条件
CuI/n-Bu3P complex; naphthalenyllithium
multistep reaction; other arylepoxy bromides; other Cu-reagent; other solvent; regioselectivity; intramolecular cyclization of epoxyarylcopper compounds; Product distribution;
参考文献
Rieke, Reuben D.; Stack, Douglas E.; Dawson, Bryan T.; Wu, Tse-Chong
Journal of Organic Chemistry, 1993 , vol. 58, # 9 p. 2483 - 2491
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; 8 h; Yield given. Yields of byproduct given;
参考文献
Bhuvaneswari; Venkatachalam; Balasubramanian
Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1499 - 1502