1-(4-硝基苯基)-2-苯基-1,2-乙二酮合成路线 （共 46 条）
反应条件
1: 19 percent / PCl3 / AlCl3 / benzene
2: 68 percent / SeO2 / acetic acid
View Scheme
参考文献
Denney, Donald B.; Denney, Dorothy Z.; Pastor, Stephen D.
Phosphorus and Sulfur and the Related Elements, 1985 , vol. 22, p. 191 - 198
反应条件
1: AlCl3 / 0.75 h / 20 °C
2: 76 percent / SeO2 / dimethylsulfoxide / 0.01 h / microwave irradiation
View Scheme
参考文献
Ramajayam; Giridhar, Rajani; Yadav
Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 7 p. 901 - 906
反应条件
1: 97 percent / 15percent aq. H2SO4 / tetrahydrofuran / Ambient temperature
2: 80 percent / NH4NO3, glacial AcOH / 16 h / Heating
View Scheme
参考文献
Armesto, Diego; Horspool, William M.; Ortiz, Maria J.; Perez-Ossorio, Rafael
Synthesis, 1988 , # 10 p. 799 - 801
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h
2: 65 percent / KMnO4, aq. MgSO4 / toluene / 30 h / 50 - 60 °C
View Scheme
参考文献
Aitken, R. Alan; Cadogan, J. I. G.; Gosney, Ian
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 101, # 1-4 p. 281 - 286
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h
2: 65 percent / KMnO4, aq. MgSO4 / toluene / 30 h / 50 - 60 °C
View Scheme
参考文献
Aitken, R. Alan; Cadogan, J. I. G.; Gosney, Ian
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 101, # 1-4 p. 281 - 286
反应条件
1: PCl5
2: 1.) Me3SnLi / 1.) THF, -78 deg C, 1 h; room temperature, 1 h, 2.) Et2O, room temperature, 15 min
3: 40 percent / HCl / tetrahydrofuran / 0.25 h / Ambient temperature
View Scheme
参考文献
Jousseaume, Bernard; Vilcot, Nathalie; Ricci, Alfredo; Tiekink, Edward R. T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2283 - 2288
反应条件
1: 1.) Me3SnLi / 1.) THF, -78 deg C, 1 h; room temperature, 1 h, 2.) Et2O, room temperature, 15 min
2: 40 percent / HCl / tetrahydrofuran / 0.25 h / Ambient temperature
View Scheme
参考文献
Jousseaume, Bernard; Vilcot, Nathalie; Ricci, Alfredo; Tiekink, Edward R. T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2283 - 2288
反应条件
tellurium (IV) oxide
3 h; Heating;
参考文献
Suzuki, Hitomi; Ninomiya, Keiji; Inouye, Masahiko
Chemistry Letters, 1985 , p. 821 - 822
反应条件
1: sodium hydride; [mmim][I] / tetrahydrofuran; mineral oil / 9 h / Inert atmosphere; Reflux
2: hydrogenchloride; water / tetrahydrofuran / 3 h / 20 °C
View Scheme
参考文献
Suzuki, Yumiko; Bakar, Abu; Tanoi, Takashi; Nomura, Naoko; Sato, Masayuki
Tetrahedron, 2011 , vol. 67, # 25 p. 4710 - 4715
参考文献
Zinin
Justus Liebigs Annalen der Chemie, 1864 , vol. Suppl.3, p. 156,160
Zeitschrift fuer Chemie, 1868 , p. 563
