potassium phosphate; Ni(PCy3)2Cl2 in ethylene glycol dimethyl ether; toluene T=120°C; 48 h; Inert atmosphere;

potassium phosphate; Ni(PCy3)2Cl2 in ethylene glycol dimethyl ether; toluene T=120°C; 48 h; Inert atmosphere;

[RhCl(cod)]2; PPh3; DABCO in toluene 100°C, 15 h;

in benzene

bis(1,5-cyclooctadiene)nickel (0); C9H11I*ClH; sodium t-butanolate in toluene T=160°C; 20 h; Inert atmosphereGloveboxSealed tube;

in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);

bis(dibenzylideneacetone)-palladium(0); tri-iso-propyl phosphine in tetrahydrofuran T=105°C; P=2660.18 Torr; 20 h; Autoclave; Catalytic behavior; ConcentrationTemperatureTime;

bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; tri-cyclo-hexyl-phosphine in toluene T=120°C; Suzuki-Miyaura coupling; 12 h;