1: 2-mercaptobenzoimidazole With sodium hydride in N,N-dimethyl-formamide
T=20°C; Inert atmosphere;
2: perfluoromethyl iodide in N,N-dimethyl-formamide
T=20°C; 14 h;
3: With hydrogenchloride in water; N,N-dimethyl-formamide
T=20°C;
in neat (no solvent)
reaction with SiF2; determination by MS and NMR; further products;; main product is CF3SiF2I;;
参考文献
Margrave, J. L.; Sharp, K. G.; Wilson, P. W.
Journal of Inorganic and Nuclear Chemistry, 1970 , vol. 32, p. 1817 - 1825
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Gmelin Handbook: C: MVol.D2, 4.2.4.4.7, page 322 - 323
in gaseous matrix
byproducts: NH2, NH, N2; F generated by microwave discharge in a flowing stream of F2 diluted with He and Ar, addn. of NH3 and CF3I, 400K, total pressure 5 Torr; not isolated, monitored spectroscopically by emmision spectroscopy;
参考文献
Zhan, Jiping; Huang, Ruiping; Zhunag, Qi; Zhang, Cunhao
Chemical Physics Letters, 1990 , vol. 174, p. 568 - 574
