1: ethyl magnesium chloride With titanium(IV) isopropylate in dichloromethane T=-78°C; 0.166667 h; Inert atmosphere; 2: benzaldehyde With (R)-3-(3,5-diphenylphenyl)-2,2'-dihydroxy-1,1'-binaphthyl in diethyl ether; dichloromethane T=0°C; 3 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; dichloromethane T=0°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 83, # 1 p. 19 - 32
Whitmore; Woodburn
Journal of the American Chemical Society, 1933 , vol. 55, p. 362
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Smith et al.
Journal of the American Chemical Society, 1939 , vol. 61, p. 3079,3082
