4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷合成路线 （共 39 条）
反应条件
in gas T=76.9°C; ΔG0; Equilibrium constantThermodynamic data;
参考文献
Chen, Qizhu; Cannell, Kevin; Nicoll, Jeremy; Dearden, David V.
Journal of the American Chemical Society, 1996 , vol. 118, # 27 p. 6335 - 6344
反应条件
KC8 in tetrahydrofuran add. of Cr(CO)6 to a suspension of KC8 under Ar at -70°C, stirring (-70°C, 1 h; 0°C, 2 h), addn. of anhydr. SnCl2 at -70°C, addn. of cryptand after 0.5 h stirring, warming to 0°C; filtn. through Kieselgur, concg. in high-vac., layering (15°C, Et2O, pentane), after 7 days Sn seperates;
参考文献
Schiemenz, Berthold; Huttner, Gottfried
Angewandte Chemie, 1993 , vol. 105, p. 295 - 296
反应条件
in toluene dropwise addn. of a soln. of Cr(CO)3(mes) to an ethylendiamine extract of a melt of nominal composition K4Sn9; cryptand then added as solid;; filtering twice of soln., left at 25°C, needles after 48h, elem. anal.;
参考文献
Eichhorn, Bryan W.; Haushalter, Robert C.; Pennington, William T.
Journal of the American Chemical Society, 1988 , vol. 110, p. 8704 - 8706
反应条件
in gas T=76.9°C; ΔG0; Equilibrium constantThermodynamic data;
参考文献
Chen, Qizhu; Cannell, Kevin; Nicoll, Jeremy; Dearden, David V.
Journal of the American Chemical Society, 1996 , vol. 118, # 27 p. 6335 - 6344
反应条件
in gas T=76.9°C; ΔG0; Equilibrium constantThermodynamic data;
参考文献
Chen, Qizhu; Cannell, Kevin; Nicoll, Jeremy; Dearden, David V.
Journal of the American Chemical Society, 1996 , vol. 118, # 27 p. 6335 - 6344
反应条件
in ethylene glycol dimethyl ether T=40°C; MechanismProduct distribution;
参考文献
Tetrahedron, , vol. 36, # 81 p. 1043 - 1050
反应条件
in methanol
Kinetics; at 25°C;
参考文献
Cox, Brian G.; Troung, Nguyen van; Schneider, Hermann
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 3285 - 3294
反应条件
in further solvent(s)
Kinetics; at 25°C in propylene carbonate;
参考文献
Cox, Brian G.; Troung, Nguyen van; Schneider, Hermann
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 3285 - 3294
反应条件
in ethylene glycol dimethyl ether
T=40°C; MechanismProduct distribution;
参考文献
Sarthou, P.; Bram, G.; Guibe, F.; Corset, J.
Tetrahedron, 1980 , vol. 36, # 81 p. 1043 - 1050
