iron(III) chloride in tetrahydrofuran 1.) -78 deg C, 2.) from -78 deg C up to 20 deg C, 18 h; various stoichiometry of MeLi-Fe(II)-complex; other alkyllithium-transition metal salt ate complexes, other temperatures, solvents and times; other epoxides and products; Product distributionMechanism;
1: sulfuric acid / acetonitrile; water / 16 h / 20 °C 2: sodium periodate; sodium hydrogencarbonate / acetonitrile; water / 1.5 h / 20 °C View Scheme
参考文献
Spannring, Peter; Yazerski, Vital; Bruijnincx, Pieter C. A.; Weckhuysen, Bert M.; Klein Gebbink, Robertus J. M.
Chemistry - A European Journal, 2013 , vol. 19, # 44 p. 15012 - 15018
