2,2,6-三甲基环己酮合成路线 (共 96 条)
反应条件
(i) NaH, (ii) aq. NaOH; Multistep reaction;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 9, p. 1466 - 1472
Zhurnal Organicheskoi Khimii, , vol. 9, # 7 p. 1436 - 1443
反应条件
water; 4,7,13,18-tetraoxa-1,10-diazabicyclo[8.5.5]eicosane in diethyl ether Ambient temperature; Product distribution;
参考文献
Bulletin de la Societe Chimique de France, , vol. 2, # 5-6 p. 283 - 288
参考文献
Journal of Organic Chemistry, , vol. 16, p. 1742,1744
反应条件
T=25°C; Equilibrium constant;
参考文献
Journal of Organic Chemistry, , vol. 21, p. 828
反应条件
das erhaltenene Produkt ist schwach rechtsdrehend;
参考文献
Journal of Organic Chemistry, , vol. 19, p. 1097,1103
反应条件
Behandeln mit Methyljodid;
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 157, p. 180
参考文献
Journal of the Chemical Society, , p. 1565,1567
反应条件
1: 1.) butyllithium, hexamethylphosphoric triamide / 1.) hexane, 0 deg C, 10 min, 2.) hexane, 4 h 2: 20 g / H2 / 10percent palladium on charcoal / ethanol / 16 h / 760 Torr 3: tin(IV) chloride / benzene / 0.25 h View Scheme
参考文献
Davis, Brian R.; Hinds, Mark G.; Johnson, Stephen J.
Australian Journal of Chemistry, 1985 , vol. 38, # 12 p. 1815 - 1825
反应条件
hydrogenchloride; chiral LiN(CH(CH3)Ph)2 Multistep reaction; by variation of the solvent and the reaction conditions, or by quenching with 1N DCl instead of HCl; the chemical and optical yield of the product was investigated involving also the recovered chiral amine; Product distributionMechanism;
参考文献
Eleveld, M. B.; Hogeveen, H.
Tetrahedron Letters, 1986 , vol. 27, # 5 p. 631 - 634
反应条件
(i), (ii) Ph3SiOH, (iii) (Ph3SiO)3VO; Multistep reaction;
参考文献
Branca,S.J. et al.
Journal of Organic Chemistry, 1977 , vol. 42, # 19 p. 3165 - 3168