1-甲基丙-2-炔基乙酸酯合成路线 （共 7 条）
反应条件
piperidine; pumice stone; zinc diacetate T=120 - 150°C;
参考文献
Alder; Wacker
Patent: US2227819 , 1938 ;
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Wacker,A.
Patent: DE710130 , 1937 ;
DRP/DRBP Org.Chem.
反应条件
1: methyl vinyl ketone With lithium diisopropyl amide in tetrahydrofuran; hexane T=-78°C; 0.75 h; Inert atmosphere; 2: acetic anhydride in tetrahydrofuran; hexane T=-78 - 25°C; Inert atmosphere;
参考文献
Dunn, Travis B.; Michael Ellis; Kofink, Christiane C.; Manning, James R.; Overman, Larry E.
Organic Letters, 2009 , vol. 11, # 24 p. 5658 - 5661
反应条件
sulfuric acid T=60 - 80°C;
参考文献
Hagemeyer
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 769
参考文献
Hagemeyer; Hull
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 2921
参考文献
Werntz
Journal of the American Chemical Society, 1935 , vol. 57, p. 205
反应条件
in benzene T=55°C; 96 h;
参考文献
Boddy; Cambie; Marsh; et al.
Australian Journal of Chemistry, 1986 , vol. 39, # 5 p. 821 - 825
反应条件
T=100°C; Oxydieren des Reaktionsprodukts mit Luft in verd.-alkoh.NaOH und Verseifen des Reaktionsprodukts mit verduennter alkoh.KOH bei 100grad;
参考文献
Werntz
Journal of the American Chemical Society, 1935 , vol. 57, p. 205
