1,1-二甲基-2-丙烯基乙酸酯合成路线 （共 69 条）
反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With bis(dibenzylideneacetone)-palladium(0) 0.0833333 h; Inert atmosphereSealed tube; 2: 2-methyl-3-buten-2-yl acetate in dimethyl sulfoxide T=50°C; 24 h; Inert atmosphereSealed tube;
参考文献
Beveridge, Ramsay E.; Batey, Robert A.
Organic Letters, 2014 , vol. 16, # 9 p. 2322 - 2325
反应条件
(i) (γ-irradiation), (ii) MeOH; Multistep reaction;
参考文献
Okubo,M.
Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 1672 - 1677
反应条件
(2R,5S)-2-cyclohexyloxy-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]octane; potassium carbonate; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide T=20°C; 18 h;
参考文献
Vasil'ev, Andrei A.; Lyubimov, Sergey E.; Serebryakov, Edward P.; Davankov, Vadim A.; Zlotin, Sergei G.
Mendeleev Communications, 2009 , vol. 19, # 2 p. 103 - 105
参考文献
Nesmejanow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1951 , p. 273,277
Chem.Abstr., 1952 , p. 882
反应条件
indium(III) chloride in acetonitrile
T=20°C; 0.5 h;
参考文献
Chakraborti, Asit K.; Gulhane, Rajesh
Tetrahedron Letters, 2003 , vol. 44, # 35 p. 6749 - 6753
反应条件
4 A molecular sieve; Bu4N[Fe(CO)3(NO)] in hexane
T=80°C; 24 h;
参考文献
Magens, Silja; Ertelt, Melanie; Jatsch, Anja; Plietker, Bernd
Organic Letters, 2008 , vol. 10, # 1 p. 53 - 56
反应条件
copper(I) bromide in dichloromethane
T=20°C; 24 h;
参考文献
Badet, B.; Julia, M.; Ramirez-Munoz, M.; Sarrazin, C. A.
Tetrahedron, 1983 , vol. 39, # 19 p. 3111 - 3126
反应条件
acetic anhydride; triethylamine in dichloromethane; water
参考文献
The Dow Chemical Company
Patent: US4667050 A1, 1987 ;
反应条件
1: 53 percent / HClO4 / CH2Cl2 / 120 h / 20 °C
2: 90 percent / CuBr / CH2Cl2 / 24 h / 20 °C
View Scheme
参考文献
Badet, B.; Julia, M.; Ramirez-Munoz, M.; Sarrazin, C. A.
Tetrahedron, 1983 , vol. 39, # 19 p. 3111 - 3126
反应条件
copper(I) bromide in dichloromethane
T=20°C; 24 h; Yield given. Yields of byproduct given;
参考文献
Badet, B.; Julia, M.; Ramirez-Munoz, M.; Sarrazin, C. A.
Tetrahedron, 1983 , vol. 39, # 19 p. 3111 - 3126
