CaH2 in toluene byproducts: H2; react. under N2, slow addn. of the alcohol via syringe to B(OH)3 (ratio 3:1) and CaH2, cooling in a water bath, slow heating to 80-90°C for 12 h after abating the H2 gas evolution; distn. of the volatile products under reduced pressure (distn. pot temp. <= 120°C), extn. with hot toluene or cyclohexane under N2;
参考文献
Cole, T. E.; Quintanilla, R.; Rodewald, S.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 55 - 64
Meerwein; Bersin
Justus Liebigs Annalen der Chemie, 1929 , vol. 476, p. 131
Full Text Show Details
Cook et al.
Journal of the Chemical Society, 1950 , p. 3125,3127
