2,4-二硝基-1-(苯氧基)苯合成路线 (共 61 条)
反应条件
sodium hydroxide in 1,4-dioxane; water
T=30°C; ionic strength O.1M (NaCl); reaction the absence of NaOH, NaOH concentration dependence; aminodephenoxylation with pyrrolidine and piperidine and hydroxydephenylation with NaOH of substituted diphenyl ethers; Rate constantMechanism;
参考文献
Emokpae, Thomas A.; Uwakwe, Patrick U.; Hirst, Jack
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 125 - 132
反应条件
in 1,4-dioxane; water
T=30°C; ionic strength O.1M (NaCl); reaction with piperidine in the presence and absence of NaOH, NaOH concentration dependence; aminodephenoxylation with pyrrolidine and piperidine and hydroxydephenylation with NaOH of substituted diphenyl ethers; Rate constantMechanism;
参考文献
Bunnett, Joseph F.; Cartano, Artemio V.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4861 - 4865
反应条件
piperidine in dimethyl sulfoxide
T=25 - 48.2°C; Kinetics;
参考文献
Le Fevre; Saunders; Turner
Journal of the Chemical Society, 1927 , p. 1171
参考文献
Borsche
Chemische Berichte, 1923 , vol. 56, p. 1490
参考文献
Borsche
Chemische Berichte, 1923 , vol. 56, p. 1490
反应条件
nitric acid
T=125°C; weiteres Edukt: rauchende Schwefelsaeure;
参考文献
Chem. Fabr. v. Heyden
Patent: DE635185 , 1934 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 252
反应条件
nickel; hydrazine hydrate in ethanol; 1,2-dichloro-ethane
T=50 - 60°C; 3 h;
参考文献
Avyyangar; Kalkote; Lugade; Nikrad; Sharma
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 10 p. 3159 - 3164
参考文献
Zahn; Kocklaenner
Zeitschrift fuer Analytische Chemie, 1954 , vol. 141, p. 183,186
反应条件
in benzene
T=30°C; other reaction partners, other solvent; Rate constant;
参考文献
Chamberlin, Rachel A.; Crampton, Michael R.; Robotham, Ian A.
Journal of Physical Organic Chemistry, 1996 , vol. 9, # 3 p. 152 - 158
反应条件
in acetonitrile
T=30°C; Rate constant;
参考文献
Emokpae, Thomas A.; Uwakwe, Patrick U.; Hirst, Jack
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 125 - 132