顺-1,3-二甲基环戊烷合成路线 (共 30 条)
反应条件
methanol; N,N,N',N'',N''-pentamethyldiethylenetriamine 1.) n-pentane, diethyl ether, a) -78 deg C, 5 min, b) RT, 1 h; other substituted 5-hexen-1-yllithiums; other Lewis bases; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 113, # 15 p. 5720 - 5727
反应条件
diethyl ether katalytische Dehydratisierung des Reaktionsprodukts und anschliessende Hydrierung an Nickel unter Druck;
参考文献
Industrial and Engineering Chemistry, , vol. 41, p. 615
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene T=45°C; var. temp., other bromoalkenes; MechanismProduct distribution;
参考文献
Australian Journal of Chemistry, , vol. 36, # 3 p. 545 - 556
反应条件
sulfated zirconia T=50°C; Product distribution; Further Variations:reaction times;
参考文献
Physical Chemistry Chemical Physics, , vol. 5, # 19 p. 4343 - 4349
反应条件
platinum T=389.9°C; selectivity of transformation, ratios of the aromatization in He or H2 carrier gas and ratios of the transformation to trans/cis isomers in hydrogen carrier gas at other temperature; Product distribution;
参考文献
Acta Chimica Academiae Scientiarum Hungaricae, , vol. 111, # 4 p. 513 - 532
反应条件
platinum T=329.9°C; rates of transformation and aromatization at fixed hydrocarbon pressure and various hydrogen partial pressure; apparent activation energy for the aromatization in He carrier gas; Product distributionKineticsThermodynamic data;
参考文献
Acta Chimica Academiae Scientiarum Hungaricae, , vol. 111, # 4 p. 513 - 532
参考文献
Journal of the American Chemical Society, , vol. 75, p. 2311,2314
反应条件
platinum T=389.9°C; selectivity of transformation, ratio of the aromatization in He or H2 carrier gas and at other temperature; optimum hydrogen pressure for C5-cyclization and C5-isomerization; Product distribution;
参考文献
Acta Chimica Academiae Scientiarum Hungaricae, , vol. 111, # 4 p. 513 - 532
反应条件
platinum T=329.9°C; rates of transformation and aromatization at fixed hydrocarbon pressure and various hydrogen partial pressure and other temperature; apparent activation energy for the aromatization in He carrier gas, thermodynamical equilibrium value for trans/cis...; Product distributionKineticsThermodynamic data;
参考文献
Acta Chimica Academiae Scientiarum Hungaricae, , vol. 111, # 4 p. 513 - 532
参考文献
Doklady Akademii Nauk SSSR, , vol. 62, p. 337,339
Chem.Abstr., , p. 2191