2-正戊丙烷-1,3-二醇合成路线 （共 12 条）
反应条件
lithium aluminium tetrahydride in diethyl ether T=20°C; 3.33333 h; Reflux;
参考文献
Shevchenko; Volynskii
Petroleum Chemistry, 2008 , vol. 48, # 2 p. 123 - 128
反应条件
1: With L-proline in N,N-dimethyl-formamide T=20°C; 2: With sodium tetrahydroborate in methanol T=0°C; Further stages.;
参考文献
Casas, Jesus; Sunden, Henrik; Cordova, Armando
Tetrahedron Letters, 2004 , vol. 45, # 32 p. 6117 - 6119
反应条件
sulfuric acid in sodium-dried diethyl ether; diethyl ether; water
反应条件
1: 87 percent / H2 / 10percent Pd-C / ethanol / Ambient temperature 2: H2O; propan-2-ol / pig pancreatic lipase, pH 7 buffer (K2HPO4-KH2PO4) View Scheme
参考文献
Journal of Organic Chemistry, , vol. 57, # 5 p. 1540 - 1554
反应条件
1: 1.) Na 2: LiAlH4 / diethyl ether / 18 h / 35 °C View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 57, # 7 p. 1966 - 1969
反应条件
in water; isopropyl alcohol pig pancreatic lipase, pH 7 buffer (K2HPO4-KH2PO4);
参考文献
Journal of Organic Chemistry, , vol. 57, # 5 p. 1540 - 1554
反应条件
1: 1.) bromine, sodium / 1.) ethanol, 60 deg C, 1 h; 2.) ether, 0 deg C 2: 1.) bromine, lithium aluminium hydride; 2.) 10percent sodium carbonate / 1.) 10 deg C, 1 h, ether; 2.) water View Scheme
参考文献
Bulletin de la Societe Chimique de France, , # 1 p. 113 - 117
反应条件
lithium aluminium tetrahydride; bromine; sodium carbonate 1.) 10 deg C, 1 h, ether; 2.) water; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Bulletin de la Societe Chimique de France, , # 1 p. 113 - 117
反应条件
1: 81 percent / pyridine / 16 h / Ambient temperature
2: 64 percent / NaH / dioxane / 7 h / Heating
3: 1.) aq.KOH, aq.HCl / 1.) ethanol, reflux, 4 h; 2.) 180°C, 30 min
View Scheme
参考文献
Chan, L. K. M.; Gemmell, P. A.; Gray, G. W.; Lacey, D.; Toyne, K. J.
Molecular Crystals and Liquid Crystals (1969-1991), 1989 , vol. 168, p. 229 - 246
反应条件
toluene-4-sulfonic acid in benzene
参考文献
Timex Corporation
Patent: US4313878 A1, 1982 ;
