2,2,6,6-四甲基哌啶氧化物合成路线 (共 284 条)
反应条件
in hexane
T=23°C; Rate constant;
参考文献
Brown, Carl E.; Neville, Anthony G.; Rayner, David M.; Ingold, Keith U.; Lusztyk, Janusz
Australian Journal of Chemistry, 1995 , vol. 48, # 2 p. 363 - 380
反应条件
pyridine; [Mn2(μ-O)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2](PF6)2; periodic acid in acetonitrile
0.25 h; Inert atmosphere;
参考文献
Amos, Ruth I. J.; Gourlay, Brendon S.; Yates, Brian F.; Schiesser, Carl H.; Lewis, Trevor W.; Smith, Jason A.
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 1 p. 170 - 176
反应条件
tert.-butylhydroperoxide; copper(l) iodide in water; acetonitrile
T=0 - 20°C; 2 h;
参考文献
Lu, Yang; Li, Yaming; Zhang, Rong; Jin, Kun; Duan, Chunying
Journal of Fluorine Chemistry, 2014 , vol. 161, p. 128 - 133
反应条件
1: iso-butyronitrile With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=-78°C; 0.333333 h; Inert atmosphere;
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical With Fe(η5-C5H5)2(PF6) in tetrahydrofuran; hexane
T=-78°C; Inert atmosphere;
参考文献
Dinca, Emanuela; Hartmann, Philip; Smrcek, Jakub; Dix, Ina; Jones, Peter G.; Jahn, Ullrich
European Journal of Organic Chemistry, 2012 , # 24 p. 4461 - 4482
反应条件
[EMIM][I] in acetonitrile-D3; deuterated toluene
T=60°C; 15 h; Schlenk techniqueInert atmosphere; Reagent/catalyst;
参考文献
Goto, Atsushi; Ohtsuki, Akimichi; Ohfuji, Haruki; Tanishima, Miho; Kaji, Hironori
Journal of the American Chemical Society, 2013 , vol. 135, # 30 p. 11131 - 11139
反应条件
tert.-butylhydroperoxide; zinc dibromide in pyridine; water
T=80°C; 16 h;
参考文献
Wu, Xiao-Feng; Bheeter, Charles Beromeo; Neumann, Helfried; Dixneuf, Pierre H.; Beller, Matthias
Chemical Communications, 2012 , vol. 48, # 100 p. 12237 - 12239
反应条件
4-(1,1-dimethylethyl)benzenethiol in benzene
0.5 h; Ambient temperature; Further byproducts given;
参考文献
Carloni; Carloni, Patricia; Damiani; Damiani, Elisabetta; Iacussi; Iacussi, Marco; Greci; Greci, Lucedio; Stipa; Stipa, Pierluigi; Cauzi; Cauzi, Daniele; Rizzoli; Rizzoli, Corrado; Sgarabotto; Sgarabotto, Paolo
Tetrahedron, 1995 , vol. 51, # 45 p. 12445 - 12452
反应条件
in benzene
0.5 h; Ambient temperature; Further byproducts given;
参考文献
Carloni; Carloni, Patricia; Damiani; Damiani, Elisabetta; Iacussi; Iacussi, Marco; Greci; Greci, Lucedio; Stipa; Stipa, Pierluigi; Cauzi; Cauzi, Daniele; Rizzoli; Rizzoli, Corrado; Sgarabotto; Sgarabotto, Paolo
Tetrahedron, 1995 , vol. 51, # 45 p. 12445 - 12452
反应条件
in benzene
0.5 h; Ambient temperature; Further byproducts given;
参考文献
Carloni; Carloni, Patricia; Damiani; Damiani, Elisabetta; Iacussi; Iacussi, Marco; Greci; Greci, Lucedio; Stipa; Stipa, Pierluigi; Cauzi; Cauzi, Daniele; Rizzoli; Rizzoli, Corrado; Sgarabotto; Sgarabotto, Paolo
Tetrahedron, 1995 , vol. 51, # 45 p. 12445 - 12452
反应条件
potassium carbonate in N,N-dimethyl-formamide
T=130°C; 40 h; Inert atmosphere;
参考文献
Zhu, Xu; Wang, Yi-Feng; Ren, Wei; Zhang, Feng-Lian; Chiba, Shunsuke
Organic Letters, 2013 , vol. 15, # 13 p. 3214 - 3217