2,2,6,6-四甲基哌啶氧化物合成路线 (共 284 条)
反应条件
di-tert-butyl peroxide
T=120°C; 12 h; Inert atmosphere;
参考文献
Guo, Sheng-Rong; Yuan, Yan-Qin; Xiang, Jian-Nan
Organic Letters, 2013 , vol. 15, # 18 p. 4654 - 4657
反应条件
1: cyclopropane carboxylic acid cyanide With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=-78°C; 0.333333 h; Inert atmosphere;
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical With Fe(η5-C5H5)2(PF6) in tetrahydrofuran; hexane
T=-78°C; Inert atmosphere;
参考文献
Dinca, Emanuela; Hartmann, Philip; Smrcek, Jakub; Dix, Ina; Jones, Peter G.; Jahn, Ullrich
European Journal of Organic Chemistry, 2012 , # 24 p. 4461 - 4482
反应条件
potassium hydroxide
T=20 - 25°C; electrolysis: Pt plates as anode and cathode, current 2 A; also with respective 4-oxonitroxyl radical; Product distribution;
参考文献
Kagan; Pozhidaeva; Zhukova; Kashparov
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 9 p. 1363 - 1364
反应条件
copper dichloride in diethyl ether
T=20°C; Inert atmosphere;
参考文献
Sorin, Geoffroy; Martinezmallorquin, Rocio; Contie, Yohan; Baralle, Alexandre; Malacria, Max; Goddard, Jean-Philippe; Fensterbank, Louis
Angewandte Chemie - International Edition, 2010 , vol. 49, # 46 p. 8721 - 8723
反应条件
in chloroform
T=45°C; 16 h; UV-irradiation;
参考文献
Cabrera-Rivera, Fanny Araceli; Ortz-Nava, Claudia; Escalante, Jaime; Hernandez-Perez, Julio M.; Ho, Minhhuy
Synlett, 2012 , vol. 23, # 7 p. 1057 - 1063
反应条件
in cyclohexane
T=18°C; Rate constant;
参考文献
Chateauneuf, J.; Lusztyk, J.; Ingold, K. U.
Journal of Organic Chemistry, 1988 , vol. 53, # 8 p. 1629 - 1632
反应条件
in hexane
T=-78°C; 0.0833333 h;
参考文献
Anderson, J. Edgar; Casarini, Daniele; Corrie, John E. T.; Lunazzi, Lodovico
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 7 p. 1299 - 1304
反应条件
in pentane
2 h; Ambient temperatureIrradiation;
参考文献
Billera, Charles F.; Dunn, Travis B.; Barry, David A.; Engel, Paul S.
Journal of Organic Chemistry, 1998 , vol. 63, # 26 p. 9763 - 9768
反应条件
in benzene-d6
Flash photolysis; Product distribution; Further Variations:Reaction partners;
参考文献
Ananchenko, Gennady; Fischer, Hanns
Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 10 p. 1887 - 1889
反应条件
di-tert-butyl peroxide
T=116.85°C; 16 h;
参考文献
Ciriano, Maria Victoria; Korth, Hans-Gert; Van Scheppingen, Wibo B.; Mulder, Peter
Journal of the American Chemical Society, 1999 , vol. 121, # 27 p. 6375 - 6381