(S)-(+)-2-戊醇合成路线 （共 77 条）
反应条件
Geschwindigkeit der Reaktion;
参考文献
Evans; Huston
Journal of Organic Chemistry, 1959 , vol. 24, p. 1178,1180
参考文献
Hills; Kenyon; Phillips
Journal of the Chemical Society, 1936 , p. 576,583
参考文献
Kasanskii et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1957 , p. 1401; engl. Ausg. S. 1422
反应条件
1: 83 percent / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 1.5 h / 25 °C 2: 93.5 percent / KOH / methanol; H2O; tetrahydrofuran / 2 h / 25 °C View Scheme
参考文献
Cheskis, B. A.; Shpiro, N. A.; Moiseenkov, A. M.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 9.1 p. 1613 - 1616
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 9 p. 1864 - 1869
参考文献
Adembri
Annali di Chimica (Rome, Italy), 1956 , vol. 46, p. 62,66,68
参考文献
Syrjanowa; Petrow
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 1593,1596,1598;engl.Ausg.S.1785,1787,1789
反应条件
NADP; tri-(hydroxymethyl)-methylamine; SADH from Thermoanaerobacter ethanolicus T=15°C; pH 8.9; temp.-dependent enantiospecificity; Rate constant;
参考文献
Pham, Van T.; Phillips, Robert S.; Ljungdahl, Lars G.
Journal of the American Chemical Society, 1989 , vol. 111, # 5 p. 1935 - 1936
反应条件
dipotassium hydrogenphosphate; phosphoric acid; EC 1.1.1.2 ketoreductase in hexane T=25°C; pH=7.3; 24 h; Equilibrium constant; Further Variations:SolventsTemperatures;
参考文献
Tewari, Yadu B.; Schantz, Michele M.; Phinney, Karen W.; Rozzell, J. David
Journal of Chemical Thermodynamics, 2005 , vol. 37, # 1 p. 89 - 96
反应条件
1: phosphorus; iodine 2: ethanol 3: acetic acid; aqueous hydrogen peroxide 4: ethanolic potassium ethylate View Scheme
参考文献
Brown; Wheeler
Journal of the American Chemical Society, 1956 , vol. 78, p. 2199,2201
参考文献
Journal of the American Chemical Society, , vol. 74, p. 4063,4066
