2,4,6-三甲基苯溴化镁合成路线 （共 186 条）
反应条件
in tetrahydrofuran
T=-65°C;
参考文献
Appel, Rolf; Gaitzsch, Thomas; Knoch, Frank; Lenz, Gerhard
Chemische Berichte, 1986 , vol. 119, # 6 p. 1977 - 1985
反应条件
in diethyl ether
dry/inert atmosphere; stirring (6 h); aq. HCl addn., ether layer evapn., hexane trituration, drying;
参考文献
Cooke, Jeffrey A.; Dixon, Craig E.; Netherton, Matthew R.; Kollegger, Gerlinde M.; Baines, Kim M.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1996 , vol. 26, # 7 p. 1205 - 1217
反应条件
C76H88Cl2FeN8P4 in tetrahydrofuran
T=25°C; 1 h; Schlenk techniqueInert atmosphere;
参考文献
Kawamura, Shintaro; Nakamura, Masaharu
Chemistry Letters, 2013 , vol. 42, # 2 p. 183 - 185
反应条件
3,3',5,5'-tetra-tert-butyl-4,4'-diphenoquinone; lithium chloride in tetrahydrofuran
参考文献
Krasovskiy, Arkady; Tishkov, Alexander; Del Amo, Vicente; Mayr, Herbert; Knochel, Paul
Angewandte Chemie - International Edition, 2006 , vol. 45, # 30 p. 5010 - 5014
反应条件
[Pd(Cl){2-[OC(Ph)2CH2]-6-(3,5-Me2C3HN2)C5H3N}] in tetrahydrofuran; toluene
Kumada reaction; 24 h; Heating;
参考文献
Wang, Zhong-Xia; Chai, Zuo-Yun
European Journal of Inorganic Chemistry, 2007 , # 28 p. 4492 - 4499
反应条件
palladium diacetate; triphenylphosphine in tetrahydrofuran
T=60°C; 20 h;
参考文献
Dong, Cheng-Guo; Yeung, Pik; Hu, Qiao-Sheng
Organic Letters, 2007 , vol. 9, # 2 p. 363 - 366
反应条件
CuCN in tetrahydrofuran
T=0 - 20°C;
参考文献
Simaan, Samah; Biali, Silvio E.
Journal of Organic Chemistry, 2004 , vol. 69, # 1 p. 95 - 98
反应条件
tetradecyl(trihexyl)phosphonium decanoate
Grignard reaction;
参考文献
Ramnial, Taramatee; Taylor, Stephanie A.; Clyburne, Jason A. C.; Walsby, Charles J.
Chemical Communications, 2007 , # 20 p. 2066 - 2068
反应条件
anhydrous iron chloride; 1,2-dichloro-ethane in tetrahydrofuran
T=25°C; 0.5 h; Ionic liquidInert atmosphere;
参考文献
Kude, Keisuke; Hayase, Shuichi; Kawatsura, Motoi; Itoh, Toshiyuki
Heteroatom Chemistry, 2011 , vol. 22, # 3-4 p. 397 - 404
反应条件
1: 2,4,6-trimethylphenylmagnesium bromide With dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; tris-(dibenzylideneacetone)dipalladium(0); zinc(II) chloride in tetrahydrofuran
T=23°C; 0.333333 h; Inert atmosphere;
2: 1-bromo-2,6-dimethyl-benzene in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=70°C; 2.5 h; Inert atmosphere;
参考文献
Calimsiz, Selcuk; Sayah, Mahmoud; Mallik, Debasis; Organ, Michael G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 11 p. 2014 - 2017
