2,4,6-三甲基苯溴化镁合成路线 （共 186 条）
参考文献
Lapkin; Lapkina
Zhurnal Obshchei Khimii, 1952 , vol. 22, p. 1602,1610; engl. Ausg. S. 1643, 1650
参考文献
Lapkin; Lapkina
Zhurnal Obshchei Khimii, 1952 , vol. 22, p. 1602,1610; engl. Ausg. S. 1643, 1650
参考文献
Lapkin; Lapkina
Zhurnal Obshchei Khimii, 1952 , vol. 22, p. 1602,1610; engl. Ausg. S. 1643, 1650
反应条件
1.1: tetrahydrofuran; diethyl ether / -78 - 0 °C / Inert atmosphere
2.1: lithium hexamethyldisilazane / tetrahydrofuran; diethyl ether / 0 - 20 °C / Inert atmosphere
2.2: 20 °C / Inert atmosphere
View Scheme
参考文献
Han, Zhengxu S.; Meyer, Angelica M.; Xu, Yibo; Zhang, Yongda; Busch, Robert; Shen, Sherry; Grinberg, Nelu; Lu, Bruce Z.; Krishnamurthy, Dhileep; Senanayake, Chris H.
Journal of Organic Chemistry, 2011 , vol. 76, # 13 p. 5480 - 5484
反应条件
water in not given
N2-atmopshere; dropwise addn. MesMgBr to GeCl4, refluxing (overnight), H2O addn.; washing (H2O), drying (MgSO4), evapn., reacrystn. (EtOH);
参考文献
Lambert, Joseph B.; Zhao, Yan; Wu, Hongwei; Tse, Winston C.; Kuhlmann, Barbara
Journal of the American Chemical Society, 1999 , vol. 121, # 21 p. 5001 - 5008
参考文献
Arnold; Liggett; Searles
Journal of the American Chemical Society, 1948 , vol. 70, p. 3938
