2,4,6-三甲基苯溴化镁合成路线 (共 186 条)
反应条件
in tetrahydrofuran Grignard reaction;
参考文献
Chemical Communications, , # 20 p. 2066 - 2068
反应条件
tetradecyl(trihexyl)phosphonium decanoate Grignard reaction;
参考文献
Chemical Communications, , # 20 p. 2066 - 2068
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; copper(I) bromide in tetrahydrofuran 20 h; Heating;
参考文献
Bennett, Martin A.; Edwards, Alison J.; Harper, Joanne R.; Khimyak, Tetyana; Willis, Anthony C.
Journal of Organometallic Chemistry, 2001 , vol. 629, # 1-2 p. 7 - 18
反应条件
in tetrahydrofuran T=0 - 20°C;
参考文献
Busacca, Carl A.; Lorenz, Jon C.; Grinberg, Nelu; Haddad, Nizar; Hrapchak, Matt; Latli, Bachir; Lee, Heewon; Sabila, Paul; Saha, Anjan; Sarvestani, Max; Shen, Sherry; Varsolona, Richard; Wei, Xudong; Senanayake, Chris H.
Organic Letters, 2005 , vol. 7, # 19 p. 4277 - 4280
反应条件
1: PCl3 / diethyl ether 2: H2O / diethyl ether View Scheme
参考文献
Beswick, Michael A.; Cromhout, Natalie L.; Harmer, Christopher N.; Palmer, Julie S.; Raithby, Paul R.; Steiner, Alexander; Verhorevoort, Kerry L.; Wright, Dominic S.
Chemical Communications, 1997 , # 6 p. 583 - 584
反应条件
diethyl ether; benzene
参考文献
Newman; Lord
Journal of the American Chemical Society, 1944 , vol. 66, p. 733
参考文献
Newman; Muth
Journal of the American Chemical Society, 1950 , vol. 72, p. 5191
Journal of the American Chemical Society, 1951 , vol. 73, p. 4629
参考文献
Newman; Muth
Journal of the American Chemical Society, 1950 , vol. 72, p. 5191
Journal of the American Chemical Society, 1951 , vol. 73, p. 4629
反应条件
1: (2R,4S)-3-[(4-methylphenyl)sulfonyl]-4-(phenylmethyl)-1,2,3-oxathiazolidine 2-oxide; 2,4,6-trimethylphenylmagnesium bromide in tetrahydrofuran T=-68°C; Inert atmosphereCooling with acetone-dry ice; 2: With lithium hexamethyldisilazane in tetrahydrofuran T=-68 - 20°C; Inert atmosphere; 3: benzaldehyde With titanium tetraethoxide in tetrahydrofuran T=20°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 9 p. 2704 - 2708
反应条件
in tetrahydrofuran T=-15 - 20°C; 3 h;
参考文献
Lee, Jae In
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 3 p. 749 - 752