2-氯-2'-异氰酸-4-硝基联苯合成路线 (共 6 条)
反应条件
2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; palladium diacetate; sodium t-butanolate in 1,4-dioxane T=120°C; Buchwald-Hartwig amination; 20 h; Inert atmosphere; chemoselective reaction;
参考文献
Dumrath, Andreas; Luebbe, Christa; Neumann, Helfried; Jackstell, Ralf; Beller, Matthias
Chemistry - A European Journal, 2011 , vol. 17, # 35 p. 9599 - 9604
反应条件
oxygen; triethylamine; [Cu3(1,3,5-benzenetricarboxylate)2] in dichloromethane T=20°C; 5 h; Product distribution / selectivity;
参考文献
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA; BASF SE; YAGHI, Omar, M.; CZAJA, Alexander, U.; WANG, Bo; LU, Zheng
Patent: WO2011/14503 A1, 2011 ;
Location in patent: Page/Page column 23-28 ;
反应条件
iridium bromide; formic acid; zinc in water T=30°C; 20 h;
参考文献
da Silva, Renato A.; Bieber, Lothar W.
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 689 - 691
反应条件
in dichloromethane T=0 - 20°C; 0.333333 h; Inert atmosphere;
参考文献
Shankaraiah, Nagula; Markandeya, Nagula; Srinivasulu, Vunnam; Sreekanth, Kokkonda; Reddy, Ch. Sanjeeva; Santos, Leonardo S.; Kamal, Ahmed
Journal of Organic Chemistry, 2011 , vol. 76, # 17 p. 7017 - 7026
反应条件
NiCuFeO(x) in anhydrous xylene 24 h; Inert atmosphereSealed tubeReflux;
参考文献
Cui, Xinjiang; Dai, Xingchao; Deng, Youquan; Shi, Feng
Chemistry - A European Journal, 2013 , vol. 19, # 11 p. 3665 - 3675
参考文献
Bucherer; Fischbeck
Journal fuer Praktische Chemie (Leipzig), 1934 , vol. <2> 140, p. 69,88