1: With magnesium; ethylene dibromide in tetrahydrofuran
T=20°C; Inert atmosphereCooling;
2: With phosphorus trichoride in tetrahydrofuran
T=0°C; Inert atmosphere;
参考文献
Nawara-Hultzsch, Agnieszka J.; Skopek, Katrin; Shima, Takanori; Barbasiewicz, Micha; Hess, Gisela D.; Skaper, Dirk; Gladysz, John A.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2010 , vol. 65, # 3 p. 414 - 424
n-butyllithium
multistep react.; other dithiane substrate, other electrophiles with potential radical probe incorporated; influence of HMPA additive; Mechanism;
参考文献
Grigg, Ronald; Markandu, Jasothara; Surendrakumar, Sivagnanasundram; Thornton-Pett, Mark; Warnock, William J.
Tetrahedron, 1992 , vol. 48, # 47 p. 10399 - 10422