in dichloromethane
NO was bubbled through the soln. of MoCl5 and CH3CN at room temp. for 1h, Ar atm.; concn., pptn. with pentane, filtration, washing with pentane, drying invac.; elem. anal.;
in water
byproducts: N oxide; a mixture of 3 parts of weight HNO3 (density : 1.314) and 5 parts of weight HCl (density : 1.156) is distilled; yielding a red gas, which becomes yellow red by condensing;; the mixture is identified in the original as N2O3Cl4;;
参考文献
Baudrimont
Liebigs Annalen der Chemie, 1846 , vol. 56, p. 87 - 87
