反应条件
trimethylphosphane in gas
evapn. of nickel atoms from a premelted ingot at ca. 1.17 kW (4.5 kV at 260mA) and co-condensation with P(CH3)3 over a period of 2 h, warming up to room temp. under N2, removing excess of P(CH3)3 by continuous evacuation; washing of reaction vessel walls with light petroleum, filtering soln. through Celite to remove unreacted nickel, removal of solvent in vacuo, recrystn. from hot ethanenitrile;
参考文献
Avent, Anthony G.; Cloke, F. Geoffrey N.; Day, Jeremy P.; Seddon, Elaine A.; Seddon, Kenneth R.; Smedley, Stephen M.
Journal of Organometallic Chemistry, 1988 , vol. 341, p. 535 - 542
