in ethylene glycol dimethyl ether Electrolysis; (N2); potential controlled electrolysis at -1,6 V (vs. AgI/Ag referenceelectrode) of soln. of Ge compd. at room temp. in presence of Me3SiCl; filtered soln. was evapd. in vac., residue was extd. with ether and solvent removed, residue was sepd. by TLC, products were identified by m. p., IR, NMR and MAS;
参考文献
Corriu, R. J. P.; Dabosi, G.; Martineau, M.
Journal of Organometallic Chemistry, 1980 , vol. 188, # 1 p. 63 - 72
in cyclohexane Irradiation (UV/VIS); dissolution of digermane in dry cyclohexane in a quartz tube, degassing in a vacuum, charging with argon, irradiation with a 110 W low pressure Hg arc lamp at room temp. for 2 h; verrifying the photoproducts by GLC and GC-MS;
参考文献
Mochida, Kunio; Wakasa, Masanobu; Sakaguchi, Yoshio; Hayashi, Hisaharu
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 6 p. 1889 - 1895
in diethyl ether under N2, to suspn. of Ph3PGeI2 in ether PhLi added dropwise (1:4 molarratio), stirred for 5 d under reflux, hydrolyzed; dried, analyzed by gas chromy.;
参考文献
Inoguchi, Yoshio; Okui, Shuko; Mochida, Kunio; Itai, Akiko
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 3 p. 974 - 977
in neat (no solvent) Ge deriv. heating with a large excess of organic reagent in a sealed tube at 150°C for 5 h, concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
in diethyl ether byproducts: MePhEtSiH; EtLi in ether was added to an equimolar amt. of silane, room temp., N2 atm.; hydrolysis, extn. (ether), evapn., not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
in diethyl ether EtLi in ether was added to an equimolar amt. of silane, room temp., 3 h, N2 atm.; pptn. (pentane), filtration, evapn., not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
in diethyl ether under N2 a soln. of a mixt. of Ph3GeCl and Ph2GeCl2 was treated with an excess of LiAlH4; after hydrolysis the organic layer was dried over Na2SO4, pumped off, chromd. (silica gel, benzene/hexane);
参考文献
Cerveau, Genevieve; Colomer, Ernesto; Corriu, Robert J.P.; Young, J. Colin
Journal of Organometallic Chemistry, 1981 , vol. 205, # 1 p. 31 - 45
