in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
in diethyl ether byproducts: MePhEtSiOMe; EtLi in ether was added to an equimolar amt. of silane, room temp., 3 h, N2 atm.; not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
in diethyl ether byproducts: (+)-MePhEtSiH; EtLi and EtBr in ether were added dropwise to an equimolar amt. of silane, room temp., 12 h, N2 atm.; filtration, evapn., not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
in acetonitrile-D3 in NMR tube; soln. of t-Bu3GeNMe2 in CD3CN heated at 85°C for 6 d; Ph3GeH added; heated at 85°C for 72 h; not isolated; monitored by (13)C NMR spectra;
参考文献
Amadoruge, Monika L.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Weinert, Charles S.
Journal of Organometallic Chemistry, 2008 , vol. 693, # 10 p. 1771 - 1778
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反应条件
in not given
参考文献
Porchia, Maria; Brianese, Nicola; Casellato, Umberto; Ossola, Franco; Rossetto, Gilberto; at al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 677 - 682
in diethyl ether EtLi and EtBr in ether were added dropwise to an equimolar amt. of silane, room temp., 24 h, N2 atm.; filtration, evapn., not sep. detected with NMR specra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
