1-(1-苯基乙烯基)-萘合成路线 （共 27 条）
反应条件
trifluoroacetic acid in dichloromethane
T=30°C; 50 h; Cooling with ice;
参考文献
Rahman, Md. Ataur; Ogawa, Osamu; Oyamada, Juzo; Kitamura, Tsugio
Synthesis, 2008 , # 23 art. no. F15508SS, p. 3755 - 3760
反应条件
sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle in water
T=120°C; Hiyama reaction; 0.333333 h; microwave irradiation;
参考文献
Alacid, Emilio; Najera, Carmen
Journal of Organic Chemistry, 2008 , vol. 73, # 6 p. 2315 - 2322
反应条件
sodium carbonate; Pd-MCM-41 in 1-methyl-pyrrolidin-2-one
T=150°C; Heck coupling; 6 h; Title compound not separated from byproducts;
参考文献
Papp, Attila; Galbacs, Gabor; Molnar, Arpad
Tetrahedron Letters, 2005 , vol. 46, # 45 p. 7725 - 7728
反应条件
1: benzoic acid hydrazide With copper(l) iodide; toluene-4-sulfonic acid; palladium dichloride in dimethyl sulfoxide; acetonitrile
T=20°C; P=760.051 Torr; 1 h;
2: 1-vinyl naphthalene in dimethyl sulfoxide; acetonitrile
T=100°C; 3 h; Overall yield = 74 percent; stereoselective reaction;
参考文献
Zhang, Yong-Gang; Liu, Xiang-Lei; He, Zeng-Yang; Li, Xi-Ming; Kang, Hong-Jian; Tian, Shi-Kai
Chemistry - A European Journal, 2014 , vol. 20, # 10 p. 2765 - 2769
反应条件
1: in tetrahydrofuran
T=-78 - 20°C;
2: With toluene-4-sulfonic acid in methanol
2 h; Heating;
参考文献
Diaz Gomez, Edison; Albert, Dieter; Mattiza, Jens; Duddeck, Helmut; Chojnowski, Julian; Cypryk, Marek
Tetrahedron Asymmetry, 2006 , vol. 17, # 11 p. 1743 - 1748
反应条件
HSZ-360-Y zeolite in various solvent(s)
T=110°C; 14 h; Yield given. Yields of byproduct given;
参考文献
Sartori, Giovanni; Bigi, Franca; Pastorio, Andrea; Porta, Cecilia; Arienti, Attilio; et al.
Tetrahedron Letters, 1995 , vol. 36, # 50 p. 9177 - 9180
反应条件
1: 56 percent / tetrahydrofuran / Ambient temperature
2: 73 percent / CuF2*2H2O / diethyl ether / 8 h / Ambient temperature
3: 74 percent / (η3-C3H5PdCl)2, tetrabutylammonium fluoride / tetrahydrofuran / 21 h / 60 °C
View Scheme
参考文献
Hatanaka, Yasuo; Goda, Ken-ichi; Hiyama, Tamejiro
Journal of Organometallic Chemistry, 1994 , vol. 465, # 1-2 p. 97 - 100
反应条件
1: 73 percent / CuF2*2H2O / diethyl ether / 8 h / Ambient temperature
2: 74 percent / (η3-C3H5PdCl)2, tetrabutylammonium fluoride / tetrahydrofuran / 21 h / 60 °C
View Scheme
参考文献
Hatanaka, Yasuo; Goda, Ken-ichi; Hiyama, Tamejiro
Journal of Organometallic Chemistry, 1994 , vol. 465, # 1-2 p. 97 - 100
反应条件
sulfuric acid; acetic acid
参考文献
Xing, Dong; Guan, Bingtao; Cai, Guixin; Fang, Zhao; Yang, Liping; Shi, Zhangjie
Organic Letters, 2006 , vol. 8, # 4 p. 693 - 696
反应条件
1.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1 h / -78 °C
1.2: 3 h / -78 - 0 °C
2.1: hydrogenchloride / tetrahydrofuran; water / 65 °C
3.1: tetrahydrofuran / 0.5 h / 0 °C
4.1: Grubb's 2nd generation catalyst; ethene / toluene / 2 h / 80 °C / 760.05 Torr
5.1: toluene-4-sulfonic acid / toluene / 50 °C / |Inert atmosphere
View Scheme
参考文献
Yoshida, Kazuhiro; Nishii, Kana; Kano, Yuto; Wada, Shiro; Yanagisawa, Akira
Journal of Organic Chemistry, 2014 , vol. 79, # 9 p. 4231 - 4239
