反式双(三乙基膦)二氯化钯(II)合成路线 （共 11 条）
反应条件
in toluene toluene soln. of W and Pd compd. (in 2:1 molar ratio) were stirred for 3 h; mixt. was stirred with activated charcoal for 0.5 h, filtered, toluene removed in vac., pentane was added for crystn., recrystd. from toluene/pentane, elem. anal.;
参考文献
Wengrovius, Jeffrey H.; Schrock, Richard R.
Organometallics, 1982 , vol. 1, p. 148 - 155
反应条件
in toluene byproducts: 1,5-cyclooctadiene; react. of educts for 2 d; solvent removed in vac., residue dissolved in ether, cooled to -30°C, pentane was added to the filtrate, crystd. at -30°C, product recrystd. from ether/pentane, elem. anal.;
参考文献
Wengrovius, Jeffrey H.; Schrock, Richard R.
Organometallics, 1982 , vol. 1, p. 148 - 155
反应条件
in chloroform heting a chloroform soln. above 45°C;
参考文献
Onitsuka, Kiyotaka; Yamamoto, Mari; Suzuki, Shinobu; Takahashi, Shigetoshi
Organometallics, 2002 , vol. 21, # 4 p. 581 - 583
参考文献
Wengrovius, Jeffrey H.; Schrock, Richard R.
Organometallics, 1982 , vol. 1, p. 148 - 155
反应条件
in ethanol; water addn. of stoich. amt. of phosphine (in alcohol) to aq. soln. of Pd-complex (pptn.); filtration, drying, recrystn. (CHCl3/hexane); elem. anal.;
参考文献
Louch, W. J.; Eaton, D. R.
Inorganica Chimica Acta, 1978 , vol. 30, p. 243 - 250
反应条件
in acetic acid a stirred suspension of PdCl2 in anhyd. CH3COOH was treated with an excess of azine, refluxed for 45 min, cooled, treated with PEt3;
参考文献
Granell, Jaime; Sales, Joaquim; Vilarrasa, Jaume; Declercq, Jean P.; Germain, Gabriel; et al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 2441 - 2446
反应条件
2 equivs. of phosphine; procedure from Inorg. Synth. 1968, 11, 108;
参考文献
Yamashita, Hiroshi; Reddy, N. Prabhakar; Tanaka, Masato
Organometallics, 1997 , vol. 16, # 24 p. 5223 - 5233
反应条件
1 equiv. of Pd compd.;
参考文献
Wengrovius, Jeffrey H.; Schrock, Richard R.
Organometallics, 1982 , vol. 1, p. 148 - 155
反应条件
in methanol stirring (90 min); solvent removal, sepn. of PEt3-complex from liquid sulphide complex; elem. anal.;
参考文献
Clark, David T.; Dillon, Keith B.; Thomas, H. Ronald; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 250 - 253
反应条件
copper(l) iodide in diethylamine to a soln. of the Pd-complex in Et2NH in presence of CuI is added the alkine at room temp. (react. time 1 h under N2); solvent is evapd., residue is treated with benzene and the soln. chromd. (Al2O3, benzene);
参考文献
Sebald, Angelika; Wrackmeyer, Bernd; Beck, Wolfgang
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1983 , vol. 38, # 1 p. 45 - 56
