2,3,5,6-四氟吡啶合成路线 （共 61 条）
反应条件
[Ni(1,2-bis(di-isopropylphosphino)ethane)(μ-H)]2; diethylphosphinoethane in 1,4-dioxane T=120°C; 72 h;
参考文献
Arevalo, Alma; Tlahuext-Aca, Adrian; Flores-Alamo, Marcos; Garcia, Juventino J.
Journal of the American Chemical Society, 2014 , vol. 136, # 12 p. 4634 - 4639
反应条件
4-(N,N-dimethlyamino)pyridine; C21H27AuN2 in dichloromethane T=40°C; 12 h; Inert atmosphere;
参考文献
Lv, Hongbin; Zhan, Jin-Hui; Cai, Yuan-Bo; Yu, Yi; Wang, Bingwu; Zhang, Jun-Long
Journal of the American Chemical Society, 2012 , vol. 134, # 39 p. 16216 - 16227,12
反应条件
catalyst: Pd on active carbon in gaseous matrix C5F5N is passed in H2 stream over catalyst (10 percent Pd/90 percent active carbon) at 320 °C.;
参考文献
Gmelin Handbook: F: PerFHalOrg.5, 4, page 115 - 148
反应条件
triethylsilane; [Rh(μ-H)(1,3-bis(diisopropylphosphanyl)propane)]2 in benzene-d6 T=50°C; 48 h; Inert atmosphere; regioselective reaction;
参考文献
Zamostna, Lada; Ahrens, Mike; Braun, Thomas
Journal of Fluorine Chemistry, 2013 , vol. 155, p. 132 - 142
反应条件
in benzene-d6 T=50°C; 48 h; Inert atmosphere; regioselective reaction;
参考文献
Zamostna, Lada; Ahrens, Mike; Braun, Thomas
Journal of Fluorine Chemistry, 2013 , vol. 155, p. 132 - 142
反应条件
trans-[PdF(4-tetrafluoropyridyl)(P(iPr)3)2] in tetrahydrofuran T=70°C; 2 h;
参考文献
Braun, Thomas; Izundu, Joseph; Steffen, Andreas; Neumann, Beate; Stammler, Hans-Georg
Dalton Transactions, 2006 , # 43 p. 5118 - 5123
反应条件
XeF2; cesium fluoride in acetonitrile T=10 - 20°C; 0.5 h;
参考文献
Bardin, V. V.; Stennikova, I. V.; Furin, G. G.; Leshina, T. V.; Yakobson, G. G.
J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 11 p. 2580 - 2588,2297 - 2303
反应条件
XeF2; cesium fluoride in acetonitrile T=10 - 20°C; 0.5 h;
参考文献
Bardin, V. V.; Stennikova, I. V.; Furin, G. G.; Leshina, T. V.; Yakobson, G. G.
J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 11 p. 2580 - 2588,2297 - 2303
反应条件
lithium aluminium tetrahydride; 1,4,7,10-tetraoxa-cyclododecane in diethyl ether 1.) 0 deg C, 10 min, 2.) r.t., 19 h;
参考文献
Chambers, Richard D.; Hall, Christopher W.; Hutchinson, John; Millar, Ross W.
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 10 p. 1705 - 1713
反应条件
in diethyl ether 0 °C (1 h), then reflux for 4 h;;
参考文献
Banks, R. E.; Burgess, J. E.; Cheng, W. M.; Haszeldine, R. N.
Journal of the Chemical Society, 1965 , p. 575 - 594
Full Text Show Details
Gmelin Handbook: F: PerFHalOrg.5, 4, page 115 - 148
Full Text Show Details
Haszeldine, R. N.; Banks, R. E.
Patent: US3317542 , 1967 ;
C.A., 1968 , vol. 68, p. 59442
