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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
哌啶戊醇
合成路线
(共 12 条)
62522-24-1
→
反应条件
2937-83-9
哌啶戊醇
反应条件
ethanol; copper oxide-chromium oxide T=250°C; P=147102 - 220652 Torr; Hydrogenation;
参考文献
Adkins et al.
Journal of the American Chemical Society, 1934 , vol. 56, p. 2425,2427
110-89-4
哌啶
+
5259-98-3
5-氯-1-戊醇
→
反应条件
2937-83-9
哌啶戊醇
反应条件
potassium carbonate; potassium iodide in acetone T=20°C; 96 h;
参考文献
Sander, Kerstin; Kottke, Tim; Hoffend, Claas; Walter, Miriam; Weizel, Lilia; Camelin, Jean-Claude; Ligneau, Xavier; Schneider, Erich H.; Seifert, Roland; Schwartz, Jean-Charles; Stark, Holger
Organic Letters, 2010 , vol. 12, # 11 p. 2578 - 2581
90715-65-4
→
反应条件
42328-04-1
+
90715-63-2
+
2937-83-9
哌啶戊醇
反应条件
sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water 1 h; Ambient temperaturespontaneous heating;
参考文献
Kafka, Stanislav; Ferles, Miloslav
Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 1 p. 78 - 85
110-89-4
哌啶
→
反应条件
2937-83-9
哌啶戊醇
反应条件
1: 85 percent / K2CO3 / butan-2-one / 7 h / Heating 2: 38 percent / Heating; reaction in nitrogen atmosphere 3: 74 percent / HCl 15percent / H2O; acetone / 0.25 h / Heating 4: 78 percent / NaOH 3M, H2O2 (30percent) / H2O; tetrahydrofuran / 1 h / Ambient temperature; spontaneous heating View Scheme
参考文献
Avison
Journal of Applied Chemistry, 1951 , vol. 1, p. 469,470
34891-25-3
→
反应条件
2937-83-9
哌啶戊醇
反应条件
aluminum oxide T=250°C;
参考文献
Glacet; Deram
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1954 , vol. 239, p. 889
Full Text Show Details
Glacet
Bulletin de la Societe Chimique de France, 1954 , p. 575,581
95650-50-3
→
反应条件
2937-83-9
哌啶戊醇
+
821-09-0
4-戊烯-1-醇
反应条件
130-140 deg C; Multistep reaction. Yields of byproduct given;
参考文献
Barbry, Didier; Hasiak, Bruno
Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 10 p. 2410 - 2414
81547-95-7
→
反应条件
2937-83-9
哌啶戊醇
反应条件
1: 38 percent / Heating; reaction in nitrogen atmosphere 2: 74 percent / HCl 15percent / H2O; acetone / 0.25 h / Heating 3: 78 percent / NaOH 3M, H2O2 (30percent) / H2O; tetrahydrofuran / 1 h / Ambient temperature; spontaneous heating View Scheme
参考文献
Kafka, Stanislav; Ferles, Miloslav
Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 1 p. 78 - 85
1119-51-3
5-溴-1-戊烯
→
反应条件
2937-83-9
哌啶戊醇
反应条件
1: 85 percent / K2CO3 / butan-2-one / 7 h / Heating 2: 38 percent / Heating; reaction in nitrogen atmosphere 3: 74 percent / HCl 15percent / H2O; acetone / 0.25 h / Heating 4: 78 percent / NaOH 3M, H2O2 (30percent) / H2O; tetrahydrofuran / 1 h / Ambient temperature; spontaneous heating View Scheme
参考文献
Kafka, Stanislav; Ferles, Miloslav
Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 1 p. 78 - 85
66035-85-6
→
反应条件
2937-83-9
哌啶戊醇
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Avison
Journal of Applied Chemistry, 1951 , vol. 1, p. 469,470
5205-39-0
戊二酸单乙酯酰氯
→
反应条件
2937-83-9
哌啶戊醇
反应条件
1: diethyl ether 2: lithium alanate; diethyl ether View Scheme
参考文献
Avison
Journal of Applied Chemistry, 1951 , vol. 1, p. 469,470
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