2,2-二甲基-3-(3-亚甲基戊-4-烯基)环氧乙烷合成路线 （共 11 条）
反应条件
dihydrogen peroxide; WO3; [CH3(n-C8H17)3N]+H2PO4- in toluene T=21°C; 3 h;
参考文献
Mahha, Yahdih; Salles, Laurent; Piquemal, Jean-Yves; Briot, Emmanuel; Atlamsani, Ahmed; Bregeault, Jean-Marie
Journal of Catalysis, 2007 , vol. 249, # 2 p. 338 - 348
反应条件
1: With N-bromosuccinmide; dimethyl sulfoxide T=10°C; 0.5 h; Inert atmosphere; 2: With 1,8-diazabicyclo[5.4.0]undec-7-ene in dimethyl sulfoxide T=0°C; 0.5 h; Inert atmosphere;
参考文献
Pigulewskii; Adrowa
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 136; engl. Ausg. S. 151
Full Text Show Details
Du Pont de Nemours and Co.
Patent: US2838524 , 1955 ;
Full Text Show Details
Du Pont de Nemours and Co.
Patent: US2692876 , 1953 ;
参考文献
Schulze, Klaus; Haufe, Guenter; Koehler, Guenther
Zeitschrift fuer Chemie (Stuttgart, Germany), 1980 , vol. 20, # 8 p. 293 - 294
参考文献
Pigulewskii; Adrowa
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 136; engl. Ausg. S. 151
反应条件
sulfuric acid 0.5 h; Heating; Further byproducts given;
参考文献
Liebigs Annalen der Chemie, , # 5 p. 761 - 769
反应条件
sulfuric acid 0.5 h; Heatingother reagent, solvent, time, temperature; MechanismProduct distribution;
参考文献
Liebigs Annalen der Chemie, , # 5 p. 761 - 769
反应条件
potassium hydrogensulfate 10 h; Heating; Further byproducts given;
参考文献
Liebigs Annalen der Chemie, , # 5 p. 761 - 769
反应条件
Dowex 50WX10 resin
T=200°C; 24 h; Further byproducts given;
参考文献
Ho, Tse-Lok; Liu, Shing-Hou
Liebigs Annalen der Chemie, 1983 , # 5 p. 761 - 769
反应条件
resin in water; acetic acid
9 h; Heating; Further byproducts given;
参考文献
Ho, Tse-Lok; Liu, Shing-Hou
Liebigs Annalen der Chemie, 1983 , # 5 p. 761 - 769
反应条件
Dowex 50WX10 resin
T=200°C; 24 h; Further byproducts given;
参考文献
Ho, Tse-Lok; Liu, Shing-Hou
Liebigs Annalen der Chemie, 1983 , # 5 p. 761 - 769
