lithium chloride; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=23 - 100°C;

trifluoroacetic acid; cobalt(II) dibromide; zinc in acetonitrile CoBr2 and Zn dust activated with CF3CO2H reacted for 5 min with allyl chloride in MeCN, aryl halide and tributylstannyl chloride added simultaneously in MeCN at room temp., stirred for 1 h at 50°C;

3-chloroprop-1-ene; trifluoroacetic acid; cobalt(II) dibromide in acetonitrile CoBr2 and Zn dust activated with CF3CO2H reacted for 5 min with allyl chloride in MeCN, reacted with aryl bromide, tributylstannyl chloride added at room temp., stirred for 30 min; hydrolyzed with NH4Cl, extd. (Et2O), chromd. (silica gel, pentane);

silver trifluoromethanesulfonate; sodium trifluoro-methanesulfonate; F-TEDA-PF6 in acetone T=65°C; 3 h; Sealed vialInert atmosphere;

sodium trifluoro-methanesulfonate; sodium hydrogencarbonate; F-TEDA-PF6; silver(l) oxide in acetone T=23 - 65°C;

water-d2; silver trifluoromethanesulfonate; F-TEDA-PF6 in acetone T=23°C; 0.333333 h; Inert atmosphere;

silver trifluoromethanesulfonate; sodium trifluoro-methanesulfonate; F-TEDA-PF6 in acetone T=65°C; 3 h; Sealed vialInert atmosphere;

1: With trifluoromethanesulfonic acid trifluoromethyl ester; sodium hydrogencarbonate in tetrahydrofuran T=-30°C; Inert atmosphere; 2: With AgPF6; F-TEDA-PF6 in tetrahydrofuran; acetone T=-30 - 23°C; Inert atmosphereDarkness;