2-苯基-1,2,3,4-四氢萘合成路线 （共 22 条）
反应条件
1: n-butyllithium / hexamethylphosphoric acid triamide / Ambient temperature
2: LTMP / 24 h / Ambient temperature
View Scheme
参考文献
Tuschka, Theodore; Naito, Katsuyuki; Rickborn, Bruce
Journal of Organic Chemistry, 1983 , vol. 48, # 1 p. 70 - 76
反应条件
1: LiAlH4
2: n-butyllithium / hexamethylphosphoric acid triamide / Ambient temperature
3: LTMP / 24 h / Ambient temperature
View Scheme
参考文献
Tuschka, Theodore; Naito, Katsuyuki; Rickborn, Bruce
Journal of Organic Chemistry, 1983 , vol. 48, # 1 p. 70 - 76
反应条件
aluminium trichloride in benzene
T=10°C; 0.25 h; Further byproducts given;
参考文献
Gelin,R. et al.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970 , vol. 270, p. 1875 - 1877
反应条件
1: AlCl3 / benzene / 0.5 h / 40 °C
2: AlCl3 / benzene / 0.92 h / 40 °C
View Scheme
参考文献
Gelin,R. et al.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970 , vol. 270, p. 1875 - 1877
反应条件
aluminium trichloride in benzene
T=40°C; 0.5 h; Further byproducts given;
参考文献
Gelin,R. et al.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970 , vol. 270, p. 1875 - 1877
反应条件
ammonia; lithium in tetrahydrofuran
T=-78°C; 1 h; other metal, temperature; Product distribution;
参考文献
Marcinow, Zbigniew; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 12 p. 3812 - 3816
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium
24 h; Ambient temperature; Yield given;
参考文献
Tuschka, Theodore; Naito, Katsuyuki; Rickborn, Bruce
Journal of Organic Chemistry, 1983 , vol. 48, # 1 p. 70 - 76
反应条件
1.1: magnesium / diethyl ether / 3.5 h / 0 °C / Inert atmosphere
1.2: Inert atmosphere; Cooling with with NaCl-ice bath
2.1: 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride / benzene / 22 h / Reflux; Inert atmosphere
View Scheme
参考文献
Reynaud, Celine; Hazimeh, Hassan; Mattalia, Jean-Marc; Marchi-Delapierre, Caroline; Chanona, Michel
Arkivoc, 2011 , vol. 2011, # 10 p. 33 - 43
反应条件
hydrogenchloride; amalgamated zinc
参考文献
v. Braun; Manz
Justus Liebigs Annalen der Chemie, 1929 , vol. 468, p. 275
反应条件
T=24 - 27°C; Destillieren des Reaktionsprodukts;
参考文献
Sisido; Nozaki
Journal of the American Chemical Society, 1948 , vol. 70, p. 1609,1610, 1611
