in neat (no solvent)
react. at 280-350 °C; complete react. after 2 1/2 h; passing through N2 at the end of the react.;; distn. off the product or removal of product with N2;;
in nitrobenzene
heating a soln. of (NPCl2)4 in C6H5NO2 with solid 90 percent KSO2F on refluxing; react. starting at 80. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with ice-water; distn. in vac.;;
in not given
react. of NH3 with (PNCl2)4 in an organic solvent;;
参考文献
Audrieth, L. F.
Record chem. Progr., 1959 , vol. 20, p. 57 - 69
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Moureu, H.; Rocquet, P.
Bulletin de la Societe Chimique de France, 1936 , vol. 3, p. 829 - 841
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Gmelin Handbook: P: MVol.C, 139, page 321 - 322
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Ratzel, G.
Diss. Heidelberg 1957, S. 8
in tetrahydrofuran
inert-atmosphere, refluxed for 24 h with stirring; THF removed by rotary evaporation, residue dried in vacuum, extracted with hot heptane, filtered, cooled (-55°C) for several days, filtered, rapid extracted with cold acetone or filtered a chloroform soln. through Florosil;
参考文献
Allrock, Harry R.; Rutt, J. Steven; Parvez, Masood
Inorganic Chemistry, 1991 , vol. 30, p. 1776 - 1782
in tetrahydrofuran
9 h; Heating; Yield given. Title compound not separated from byproducts;
参考文献
Mitropol'skaya, G. I.; Kireev, V. V.; Korshak, V. V.; Goryaev, A. A.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 11 p. 2486 - 2491,2197 - 2201
in tetrahydrofuran
9 h; Heating; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mitropol'skaya, G. I.; Kireev, V. V.; Korshak, V. V.; Goryaev, A. A.
J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 11 p. 2486 - 2491,2197 - 2201
sulfuric acid in not given
evolution of HCl on boiling with hot H2SO4;;
参考文献
Stokes, H. N.
American Chemical Journal, 1895 , vol. 17, p. 275 - 290
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Stokes, H. N.
American Chemical Journal, 1896 , vol. 18, p. 780 - 789
Full Text Show Details
Stokes, H. N.
American Chemical Journal, 1898 , vol. 20, p. 740 - 760
