二(环戊二烯基)二氟钛(IV)合成路线 （共 18 条）
反应条件
in dichloromethane at 20°C, 4 h;
参考文献
Gmelin Handbook: F: PerFHalOrg.2, 1.1.6.11, page 32 - 49
参考文献
Gmelin Handbook: Ag: MVol.B5, 1.1.2, page 6 - 8
Full Text Show Details
King, R. B.; Zipperer, W. C.
Inorganic Chemistry, 1972 , vol. 11, p. 2119 - 2125
反应条件
aniline or pyridine in not given react. of (cp2TiMe(NH3))PF6 with aniline or pyridine;
参考文献
Bochmann, Manfred; Wilson, Ladislav M.
Journal of the Chemical Society, Chemical Communications, 1986 , # 21 p. 1610 - 1611
反应条件
in acetonitrile addn. of acetonitrile to ((cp2TiMe)BF4)n;; acetonitrile-complex not isolated;;
参考文献
Bochmann, Manfred; Wilson, Ladislav M.
Journal of the Chemical Society, Chemical Communications, 1986 , # 21 p. 1610 - 1611
反应条件
in dichloromethane under Ar atm. Cp2TiCl2 was added to soln. triorganotin fluoride in CH2Cl2 and stirred for 3 h at 35°C; solvent was evapd. in vacuo - products were not separated;
参考文献
Bares, Josef; Novak, Petr; Nadvornik, Milan; Jambor, Roman; Lebl, Tomas; Cisarova, Ivana; Ruzicka, Ales; Holecek, Jaroslav
Organometallics, 2004 , vol. 23, # 12 p. 2967 - 2971
反应条件
in benzene inert atmosphere;
参考文献
Luinstra, Gerrit A.
Journal of Organometallic Chemistry, 1996 , vol. 517, # 1-2 p. 209 - 215
反应条件
in not given equimolar quantities;
参考文献
Seyam, Afif; Samha, Hussein; Hodali, Hamdallah
Gazzetta Chimica Italiana, 1990 , vol. 120, p. 527 - 530
反应条件
hydrogenchloride in not given refluxing Ti-complex with excess HCl for 15 min; pptn. on cooling, filtration, drying (vac.);
参考文献
Nath, Dina; Sharma, R. K.; Bhat, A. N.
Inorganica Chimica Acta, 1976 , vol. 20, p. 109 - 112
