四氯双(四氢呋喃)合钛(IV)合成路线 （共 17 条）
反应条件
in tetrahydrofuran N2; non-aqueous SnCl2; educts mixed, left at 293 K, within 293 K pptn.,; ppt. washed with THF, dried in vac., elem. anal.; after condensation of soln., crystalline TiCl3(THF)3 was isolated;
参考文献
Janas, Zofia; Sobota, Piotr; Lis, Tadeusz
Polyhedron, 1988 , vol. 7, p. 2655 - 2658
反应条件
in tetrahydrofuran byproducts: (2)H2; dropwise addn. of a soln. of (TiCl4(THF)2) with stirring to a stirred soln. of deutered Ti-compd. in THF under Ar, evolution of D2 for 4 h; concn. of reaction mixt., pptn., elem. anal.;
参考文献
Aleandri, Lorraine E.; Becke, Sigurd; Bogdanovic, Borislav; Jones, Deborah J.; Roziere, Jacques
Journal of Organometallic Chemistry, 1994 , vol. 472, # 1.2 p. 97 - 112
反应条件
in tetrahydrofuran (N2); standard Schlenk technique; B compd. (1 equiv.) and NaH were reacted in THF; obtained soln. was added to soln. of Ti complex in THF at room temp.; mixt. was stirred overnight; solvent removed; extd. (THF/toluene, 1/5); concd.; stood at room temp. for 3 d;
参考文献
Organometallics, , vol. 23, # 18 p. 4301 - 4307
反应条件
in not given NaC5H5 reacted with TiCl4(THF)2;
参考文献
Gomez-Ruiz, Santiago; Gallego, Beatriz; Zizak, Zeljko; Hey-Hawkins, Evamarie; Juranic, Zorica D.; Kaluderovic, Goran N.
Polyhedron, 2010 , vol. 29, # 1 p. 354 - 360
反应条件
in tetrahydrofuran T=0 - 20°C; Inert atmosphere;
参考文献
Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Organometallics, 2012 , vol. 31, # 24 p. 8544 - 8555
反应条件
in not given NaC5H4Me reacted with TiCl4(THF)2;
参考文献
Gomez-Ruiz, Santiago; Gallego, Beatriz; Zizak, Zeljko; Hey-Hawkins, Evamarie; Juranic, Zorica D.; Kaluderovic, Goran N.
Polyhedron, 2010 , vol. 29, # 1 p. 354 - 360
反应条件
in tetrahydrofuran
byproducts: LiCl; all manipulations under purified N2; soln. of Li and Ti compds. stirred overnight at room temp., stirred for 8 h; volatiles removed in vac., twice stirred with Et2O, solvent removed in vac., extd. with Et2O, concd. cooled to -80°C, elem. anal.;
参考文献
Van Meerendonk, Wouter J.; Schroeder, Kai; Brussee, Edward A. C.; Meetsma, Auke; Hessen, Bart; Teuben, Jan H.
European Journal of Inorganic Chemistry, 2003 , # 3 p. 427 - 432
