iodosylbenzene; (salen)MnIII in acetonitrile T=25°C; oxidation of aryl methyl sulfoxides by generated in situ oxo(salen)manganese(V)complexes; effect of complex substituent on the reaction rate; reactivity-selectivity principle; effect of adding trichloroacetic acid; Rate constant;
参考文献
Chellamani, Arunachalam; Kulanthaipandi, Periasamy; Rajagopal, Seenivasan
Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2232 - 2239
in N,N-dimethyl-formamide mixt. (Ph3BiMe)(BF4), sodium benzenesulfinate dihydrate, and DMF was stirred at room temp. for 2 h; water and Et2O was added and stirred, organic phase was separated and dried over MgSO4 and evapd.;
