water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: butane; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 3.7percent) and TLC;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: butane; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 34.3percent) and TLC;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: butane; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 36.7percent) and TLC;

bromobenzene; water; calcium in gas Ca vaporized at 900°C in vac. (ca. 5E-3 Torr), Me3SiGeMe3 introduced as vapor, mixed vapors condensed on cold (77 K) walls, warmed to room temp., excess of C6H5Br admitted as vapor, left to stand for 1 h, hydrolyzed with water; org layer extd. with ether, products identified by GC-MASS, GLC;

calcium in water 1 h; Ambient temperature;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: C6H6; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 5.4percent) and TLC;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: C6H6; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 45.3percent) and TLC;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: C6H6; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (yield 46.2percent) and TLC;

water in N,N,N',N',N'',N''-hexamethylphosphoric triamide byproducts: C6H6; equimolar amts.; addn. of Bu4NF to Ge-compd., stirring at room temp. for5 min, addn. of org. halide, stirring at room temp. for 24 h, water add n.; extn. of org. layer (ether), drying, concn. (vac.), gas chromy. (trace yield) and TLC;

bis(η3-allyl-μ-chloropalladium(II)) in toluene Pd-complex, P(OEt)3, toluene, 110°C, 4,5 h;;