三(1,2-二甲基丙基)-硼烷合成路线 （共 2 条）
反应条件
in tetrahydrofuran 2-methyl-2-butene was treated with BH3*SMe2 (molar ratio 3:1) in THF at25°C; detected by (11)B NMR spectra;
参考文献
Brown, Herbert C.; Racherla, Uday S.
Journal of the American Chemical Society, 1983 , vol. 105, p. 6506 - 6508
反应条件
n-butyllithium in tetrahydrofuran; pentane byproducts: isobutylene; (N2); to stirred soln. of boranederiv. in THF was dropwise added pentane soln. of LiBu at -78°C, then mixt. was allowed to warm up to room temp.; not isolated, detected by (11)B-NMR;
参考文献
Brown, Herbert C.; Kramer, Gary W.; Hubbard, John L.; Krishnamurthy, S.
Journal of Organometallic Chemistry, 1980 , vol. 188, # 1 p. 1 - 10
