potassium carbonate in ethanol T=50°C; 48 h;

tetra-(n-butyl)ammonium iodide in tetrahydrofuran

potassium carbonate; potassium iodide in acetone 6 h; Heating;

potassium hydroxide in hexane; ethyl acetate; acetonitrile

nachfolgend Kochen mit Wasser;

暂无反应条件数据

3-chloro-benzenecarboperoxoic acid in dichloromethane T=0 - 20°C; Inert atmosphere;

1: NaOEt / ethanol; tetrahydrofuran / a) -15 deg C, 3 h, b) 4 deg C, 12 h 2: xylene / 3 h / Heating 3: 93 percent / KOH / ethanol / 1.5 h / Heating 4: 73 percent / copper chromite / quinoline / 3 h / 230 °C 5: acetic acid / CH2Cl2 / 2 h / Ambient temperature 6: 1.) iodomethane / 1.) THF, from 0 deg C to 4 deg C, 30 h, 2.) water, 80 deg C, 3.5 h 7: H2, NH3 / Raney nickel / ethanol / 48 h / 2508 Torr / Ambient temperature 8: 1.) NaOEt / 1.) ethanol, 0 deg C, 1 h, 2.) ethanol, RT, 3 h 9: H2 / 10percent Pd/C / ethanol / 48 h / 2508 Torr / Ambient temperature 10: Fremy's salt, aq. KH2PO4 / acetone / 4 h / 0 °C 11: 1.) t-BuOK / 1.) THF, 0 deg C, 1 h, 2.) THF, RT, 3 h 12: p-toluenesulfonic acid / acetonitrile / 5 h / Ambient temperature 13: NaHCO3 / ethanol / 3 h / Heating 14: CH2Cl2 / 3 h / Ambient temperature 15: PhI(OCOCF3)2 (PIFA) / various solvent(s) / 0.33 h / Ambient temperature View Scheme