toluene-4-sulfonic acid; triphenylphosphine; bis(acetylacetonato) palladium T=100°C; P=15001.5 Torr; 4 h;

bis(acetylacetonato) palladium; toluene-4-sulfonic acid; triphenylphosphine T=100°C; P=15201 Torr; 3 h; Autoclaveneat (no solvent); regioselective reaction;

1: carbon monoxide; glycerol With bis(acetylacetonato) palladium; toluene-4-sulfonic acid; triphenylphosphine T=100°C; P=15001.5 Torr; 3 h; Autoclaveneat (no solvent); 2: isobutene T=100°C; P=15001.5 Torr; Autoclaveneat (no solvent); regioselective reaction;

potassium tert-butylate in tert-butyl alcohol

dihydrogen peroxide T=100°C; 3 h;

H2O HCl or phosphate buffer T=25°C; rate and equilibrium constant of hydrolysis at nionic strength 0.1; Product distributionKineticsMechanism;