四(2,2,2-三氟乙基)原硅酸盐合成路线 （共 6 条）
反应条件
tetrachlorosilane T=20°C;
参考文献
Swamy, K.C. Kumara; Chandrasekhar; Harland, John J.; Holmes, Joan M.; Day, Roberta O.; Holmes, Robert R.
Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2341 - 2348
反应条件
in Petroleum ether dropwise addn. of soln. of TiCl4 in petroleum ether (40-60°C) to soln. of 1-trialkoxysilyl 2-phenylhydrazine (equimolar amts., 0 to -10°C, under dry nitrogen), ppt. filtered in a cold atm. of dry N2; washed, dried under reduced pressure; elem. anal.;
参考文献
Narula, Suraj P.; Kapur, Neeta; Rana, Chhaju R.; Malhotra, Rajesh
Inorganica Chimica Acta, 1989 , vol. 159, p. 87 - 92
反应条件
in Petroleum ether dropwise addn. of soln. of SnCl4 in petroleum ether (40-60°C) to soln. of 1-trialkoxysilyl 2-phenylhydrazine (equimolar amts., 0 to -10°C, under dry nitrogen), ppt. filtered in a cold atm. of dry N2; washed, dried under reduced pressure; elem. anal.;
参考文献
Narula, Suraj P.; Kapur, Neeta; Rana, Chhaju R.; Malhotra, Rajesh
Inorganica Chimica Acta, 1989 , vol. 159, p. 87 - 92
反应条件
triethylamine in tetrahydrofuran T=20°C; 24 h;
参考文献
Tozawa, Takashi; Yamane, Yoshinobu; Mukaiyama, Teruaki
Chemistry Letters, 2005 , vol. 34, # 12 p. 1586 - 1587
反应条件
in tetrahydrofuran T=20°C;
参考文献
Tozawa, Takashi; Yamane, Yoshinobu; Mukaiyama, Teruaki
Chemistry Letters, 2005 , vol. 34, # 12 p. 1586 - 1587
反应条件
in tetrahydrofuran
T=20°C;
参考文献
Tozawa, Takashi; Yamane, Yoshinobu; Mukaiyama, Teruaki
Chemistry Letters, 2005 , vol. 34, # 12 p. 1586 - 1587
