1-苄基-4-三氟甲基苯合成路线 （共 33 条）
反应条件
(C6H5CON2C3H(CF3)2O)Ni(II)(tris(4-dimethylamino)pyridine) in tetrahydrofuran T=70°C; 24 h; Inert atmosphere;
参考文献
Someya, Chika I.; Inoue, Shigeyoshi; Krackl, Sebastian; Irran, Elisabeth; Enthaler, Stephan
European Journal of Inorganic Chemistry, 2012 , # 8 p. 1269 - 1277
反应条件
1: 91 percent / Et3N; DMAP / tetrahydrofuran / 16 h 2: 94 percent / Pd(OAc)2; PPh3; K3PO4 / toluene / 16 h / 90 °C View Scheme
参考文献
McLaughlin, Mark
Organic Letters, 2005 , vol. 7, # 22 p. 4875 - 4878
反应条件
Pd0(tris(tert-butyl)phosphine)2; potassium tetrakis(pentafluorophenyl)-borate in toluene T=23°C; 16 h; Inert atmosphere;
参考文献
Durak, Landon J.; Lewis, Jared C.
Organometallics, 2014 , vol. 33, # 3 p. 620 - 623
反应条件
1: diethyl ether 2: phosphorus, aq. HI / Heating View Scheme
参考文献
Kozachuk,D.N. et al.
Journal of Organic Chemistry USSR (English Translation), 1971 , vol. 7, p. 1976 - 1981
Zhurnal Organicheskoi Khimii, 1971 , vol. 7, # 9 p. 1906 - 1911
反应条件
1: diethyl ether 2: phosphorus, aq. HI / Heating View Scheme
参考文献
Kozachuk,D.N. et al.
Journal of Organic Chemistry USSR (English Translation), 1971 , vol. 7, p. 1976 - 1981
Zhurnal Organicheskoi Khimii, 1971 , vol. 7, # 9 p. 1906 - 1911
反应条件
1: diethyl ether / 0.25 h / 0 °C 2: bis(1,5-cyclooctadiene)nickel (0); diphenylcyclohexyl phosphine; cesium fluoride / 1,4-dioxane / 24 h / 40 °C / |Inert atmosphere; |Glovebox View Scheme
参考文献
Maity, Prantik; Shacklady-Mcatee, Danielle M.; Yap, Glenn P. A.; Sirianni, Eric R.; Watson, Mary P.
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 280 - 285
反应条件
1: diethyl ether 2: hypophosphorous acid; iodine / acetic acid / 60 °C View Scheme
参考文献
Meng, Li; Su, Jihu; Zha, Zhenggen; Zhang, Li; Zhang, Zhenlei; Wang, Zhiyong
Chemistry - A European Journal, 2013 , vol. 19, # 18 p. 5542 - 5545
反应条件
1: diethyl ether 2: hypophosphorous acid; iodine / acetic acid / 60 °C View Scheme
参考文献
Meng, Li; Su, Jihu; Zha, Zhenggen; Zhang, Li; Zhang, Zhenlei; Wang, Zhiyong
Chemistry - A European Journal, 2013 , vol. 19, # 18 p. 5542 - 5545
反应条件
1.1: sodium hydride / mineral oil; N,N-dimethyl acetamide / 0.17 h / 0 °C / |Inert atmosphere 1.2: 0.5 h / 20 °C / |Inert atmosphere 2.1: sodium hydride / mineral oil; N,N-dimethyl acetamide / 0.17 h / 0 °C / |Inert atmosphere 2.2: 2 h / 20 °C / |Inert atmosphere 3.1: bis[2-(diphenylphosphino)phenyl] ether; [Pd(CH3CN)4]*[BF4]2; potassium carbonate / N,N-dimethyl-formamide / 1 h / 60 °C / |Inert atmosphere View Scheme
参考文献
Yoon, Sangeun; Hong, Myeng Chan; Rhee, Hakjune
Journal of Organic Chemistry, 2014 , vol. 79, # 9 p. 4206 - 4211
反应条件
sodium tetrahydroborate in diethylene glycol dimethyl ether; water T=45°C; 24 h; var. amount of NaBH4, var. time; Rate constant;
参考文献
Liu, Kwang-Ting; Huang, Huei-Chin
Journal of the Chinese Chemical Society, 1997 , vol. 44, # 3 p. 249 - 252
