2,3-二氢-1,2,3-甲桥-1H-茚合成路线 (共 10 条)
反应条件
n-butyllithium in diethyl ether; hexane T=-60°C; 1 h;
参考文献
Kjell,D.P.; Sheridan,R.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 4111
反应条件
1: hydrazine hydrate / methanol / 72 h / Ambient temperature 2: benzene 3: CD2Cl2 / 1.5 h / -78 °C / Irradiation View Scheme
参考文献
Kjell,D.P.; Sheridan,R.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 4111
反应条件
in dichloromethane-d2 T=-78°C; 1.5 h; Irradiation;
参考文献
Kjell,D.P.; Sheridan,R.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 4111
反应条件
1: benzene 2: CD2Cl2 / 1.5 h / -78 °C / Irradiation View Scheme
参考文献
Kjell,D.P.; Sheridan,R.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 4111
反应条件
pyridine in deuterated toluene T=-75°C; 1 h; Irradiation; Mechanism;
参考文献
Burger, Ulrich; Schmidlin, Serge P.; Mareda, Jiri
Phosphorus, Sulfur and Silicon and the Related Elements, 1993 , vol. 74, # 1-4 p. 417 - 418
反应条件
pyridine in deuterated toluene T=-75°C; Irradiation; Mechanism;
参考文献
Burger, Ulrich; Gmuender, Christian; Schmidlin, Serge; Bernardinelli, Gerald
Helvetica Chimica Acta, 1990 , vol. 73, # 6 p. 1724 - 1729
反应条件
T=776.85°C; var. temp.; Product distributionMechanism;
参考文献
Laskin, Alexander; Lifshitz, Assa
Israel Journal of Chemistry, 1996 , vol. 36, # 3 p. 257 - 261
反应条件
1: 68 percent / BuLi, TsCl
2: 60 percent / diethyl ether / -90 °C
View Scheme
参考文献
Schlueter, Arnulf-Dieter; Belzner, Johannes; Heywang, Ulrich; Szeimies, Guenter
Tetrahedron Letters, 1983 , vol. 24, # 9 p. 891 - 894
反应条件
in tetrachloromethane
T=75°C;
参考文献
Kjell,D.P.; Sheridan,R.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 4111
反应条件
in acetone; acetonitrile
T=150°C; half lifes, with and without variety of solvents, deuterated solvent, and catalysts at various temperatures; MechanismProduct distribution;
参考文献
Kjell, Douglas P.; Sheridan, Robert S.
Tetrahedron Letters, 1985 , vol. 26, # 47 p. 5731 - 5734